The Φ equation in Griffiths' Introduction to QM

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SUMMARY

The forum discussion centers on the Φ equation in Griffiths' "Introduction to Quantum Mechanics," specifically regarding the general solution of the form \(Ae^{im\phi} + Be^{-im\phi}\). Participants note that Griffiths simplifies the solution to \(Ae^{im\phi}\) and absorbs the constant A into \(\Theta\), while allowing m to be negative to cover the \(Be^{-im\phi}\) case. The discussion highlights the importance of integer values for m to ensure uniqueness of wave functions under rotations and addresses the degeneracy of eigenvalues for the operator \(\hat{L}_z\). Participants express frustration with Griffiths' approach, suggesting a need for clearer explanations in quantum mechanics.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly angular momentum.
  • Familiarity with eigenfunctions and eigenvalues in quantum mechanics.
  • Knowledge of spherical harmonics and their significance in quantum systems.
  • Basic grasp of complex exponentials and their applications in wave functions.
NEXT STEPS
  • Study the derivation of eigenfunctions for the operator \(\hat{L}_z = -i \hbar \partial_{\varphi}\).
  • Explore the concept of degenerate eigenvalues in quantum mechanics.
  • Review Griffiths' "Introduction to Quantum Mechanics," focusing on sections covering angular momentum and eigenstates.
  • Investigate the implications of integer quantum numbers in wave function uniqueness and symmetry.
USEFUL FOR

Students of quantum mechanics, educators seeking to clarify angular momentum concepts, and anyone analyzing Griffiths' approach to quantum mechanics in relation to eigenvalue problems.

hoalacanhdk
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Why from Φ eq in page 136, he did not derive the solution in this form $Ae^{imφ}+Be^{-imφ}$https://drive.google.com/open?id=1thokDDIVDytck1-2HI3qyiG07mAMO1nc
 
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The general solution is indeed as you say, ##Ae^{im\phi}+Be^{-im\phi}## however it seems (for reasons that are unclear to me) that he considers only the specific solution ##Ae^{im\phi}## and he says that the constant A is absorbed by ##\Theta## and that he also covers the other specific solution ##Be^{-im\phi}## by allowing m to become negative.
 
It's because in the end, he wants a solution which is an eigenfunction of ##\hat L_z##.

Anyway, it's just a choice of how to label the solutions. For ##m=1##, for example, you could say there are two solutions, ##e^{+i\phi}## and ##e^{-i\phi}##, or you could instead say there's one state labeled ##m=1## and one labeled ##m=-1##. Either way, you're accounting for all of the solutions.
 
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But why he didn't use the combination of two solutions simultaneously? I think exp(-1)+exp(1) is a different solution from either exp(-1) or exp(1)
 
The quoted passage comes from the second edition of "Introduction to Quantum Mechanics" by Griffiths (I just received my copy of the new third edition). @hoalacanhdk, have you covered section 3.3, in particular, the paragraph on page 102 that deals with degenerate eigenvalues?
 
hoalacanhdk said:
But why he didn't use the combination of two solutions simultaneously? I think exp(-1)+exp(1) is a different solution from either exp(-1) or exp(1)

All Griffiths wants to do is prove that ##m## must be an integer. He does that for the simple solution ##e^{im\phi}##. It looks harder to prove this for the more general solution ##Ae^{im\phi} + Be^{-im \phi}##. And, I must admit, I don't immediately see a good argument that allows the simplification. (Perhaps someone else can?)

After that, the ##\theta## equation depends only on ##m^2##, hence you get the same spherical harmonics for ##m## and ##-m##. The general solution, therefore, ends up the same, whether you consider the solutions of the angular equation to be ##e^{im\phi}## for integer ##m##; or, ##Ae^{im\phi} + Be^{-im \phi}## for ##m \ge 0##.
 
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Well, again it seems to me the best advice is to use another QM textbook ;-)). If you look for eigenvalues of ##\hat{L}_z=-\mathrm{i} \hbar \partial_{\varphi}## you get unique solutions ##u_m(\varphi)=\exp(\mathrm{i} m \varphi)/\sqrt{2 \pi}## with the eigenvalues being ##m \hbar##.

A short answer, why ##m## should be integer is that you want uniqueness of the wave functions under rotations by ##2 \pi## aroud the ##z## axis. This is an incomplete argument however, because in quantum mechanics the absolute phase doesn't count. A more complete answer is that you get a complete orthonormal set of functions by this set when ##m \in \mathbb{Z}##.

If you look for the eigenfunctions of ##\hat{L}_z^2## from this it's clear that for each eigenvalue (except 0) the eigenvalue is degenerate, i.e., for each possible eigenvalue you have two linearly independent solutions, which you can choose of course as the eigenstates of ##\hat{L}_z##, i.e., ##u_{\pm m}(\varphi)## for each ##m## (with the eigenvalue ##\hbar^2 m^2## for ##\hat{L}_z^2##). You can also choose ##\cos(m \varphi)## or ##\sin(m \varphi)##. Of course, all these sets form again a complete set of orthogonal functions on ##\mathrm{L}^2([0,2 \pi])##, but why you would bother the students with a case of degenerate eigenvalues where you can much simpler treat the problem by first looking for the eigenvalues and eigenstates of ##\hat{L}_z##, I can't tell :-((.
 
vanhees71 said:
Well, again it seems to me the best advice is to use another QM textbook ;-)). If you look for eigenvalues of ##\hat{L}_z=-\mathrm{i} \hbar \partial_{\varphi}## you get unique solutions ##u_m(\varphi)=\exp(\mathrm{i} m \varphi)/\sqrt{2 \pi}## with the eigenvalues being ##m \hbar##.

A short answer, why ##m## should be integer is that you want uniqueness of the wave functions under rotations by ##2 \pi## aroud the ##z## axis. This is an incomplete argument however, because in quantum mechanics the absolute phase doesn't count. A more complete answer is that you get a complete orthonormal set of functions by this set when ##m \in \mathbb{Z}##.

If you look for the eigenfunctions of ##\hat{L}_z^2## from this it's clear that for each eigenvalue (except 0) the eigenvalue is degenerate, i.e., for each possible eigenvalue you have two linearly independent solutions, which you can choose of course as the eigenstates of ##\hat{L}_z##, i.e., ##u_{\pm m}(\varphi)## for each ##m## (with the eigenvalue ##\hbar^2 m^2## for ##\hat{L}_z^2##). You can also choose ##\cos(m \varphi)## or ##\sin(m \varphi)##. Of course, all these sets form again a complete set of orthogonal functions on ##\mathrm{L}^2([0,2 \pi])##, but why you would bother the students with a case of degenerate eigenvalues where you can much simpler treat the problem by first looking for the eigenvalues and eigenstates of ##\hat{L}_z##, I can't tell :-((.

In Griffiths' defence, the footnote in the above extract points this out as a flaw in the current argument and promises a more compelling proof when he gets to angular momentum.
 
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I'm so angry about Griffiths's QM text, because he's so brillant with his E&M textbook. Why wasn't he as careful with his QM book? :-(
 

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