The shielding effect and effective nuclear charge are crucial concepts in understanding atomic structure. The nuclear charge refers to the total positive charge of an atom's nucleus, determined by the number of protons. However, the effective nuclear charge, which influences the attraction between the nucleus and valence electrons, is always lower than the actual nuclear charge due to the shielding effect. This effect arises in multi-electron atoms where electrons repel each other, reducing the overall attraction felt by valence electrons from the nucleus. Core electrons, located closer to the nucleus, are more effective at shielding valence electrons from the full nuclear charge due to their proximity. The effective nuclear charge can be approximated by subtracting the number of core electrons from the total number of protons, highlighting the balance of attractive and repulsive forces within the atom.