The superheating of distilled water in microwave oven

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SUMMARY

The discussion centers on the phenomenon of superheating distilled water in a microwave oven. It is established that superheating occurs due to a lack of nucleation sites for bubble formation, which prevents the water from boiling until it is disturbed. When a smooth container, such as a glass, is used, the absence of imperfections inhibits bubble formation. Introducing a spoon or other object disrupts the surface tension, allowing steam bubbles to form and escape violently.

PREREQUISITES
  • Understanding of microwave heating principles
  • Knowledge of nucleation sites in chemistry
  • Familiarity with the properties of distilled water
  • Basic concepts of heat transfer and convection
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  • Research the principles of nucleation in liquids
  • Learn about the thermal properties of water and superheating
  • Explore the differences between heating methods: microwave vs. stovetop
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This discussion is beneficial for chemists, culinary professionals, and anyone interested in the safe use of microwave ovens for heating liquids.

superkaho
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As we know, the heating principle of microwave oven is by the vibration of water molecules inside the food. However, it is reminded that a cup of water should not be heated by the oven, otherwise, water would be overheating but not boils. Once it was stimulated, it boils.

From the prespective of chemistry, can anyone explain me the reason? thanks in advance.
 
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It's my understanding that its typically caused by a lack of nucleation sites on which bubbles form and rise. That and there isn't a lot of convection going on due to a different heat gradient than that encountered with a stove, for example.

Water superheats in a glass (smoother than a pot) with no nucleation sites for bubbles to form, spoon or something else breaks surface tension and introduces nucleation spot causing steam bubble to exit violently.

Could be wrong, wouldn't be the first time.
 

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