Thermal Physics Kittel chapter 6 -- Entropy of mixing problem

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SUMMARY

The discussion centers on the entropy of mixing problem as presented in Chapter 6 of "Thermal Physics" by Kittel. A participant has been struggling to derive the change in entropy, which is established as 2Nlog(2). The conversation highlights the importance of clear presentation of mathematical work, with suggestions to use LaTeX for better readability in future posts.

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  • Study the derivation of entropy in mixing scenarios from "Thermal Physics" by Kittel
  • Learn how to effectively use LaTeX for formatting mathematical equations
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bluepilotg-2_07
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Homework Statement
Suppose that a system of N atoms of type A is placed
in diffusive contact with a system of N atoms of type B at the same temperature
and volume. Show that after diffusive equilibrium is reached the total entropy
is increased by 2N log 2. The entropy increase 2N log 2 is known as the entropy
of mixing. If the atoms are identical (A = B), show that there is no increase in
entropy when diffusive contact is established. The difference in the results has
been called the Gibbs paradox.
Relevant Equations
sigma = log(g), mu = tau*log(N/V*n_Q), sigma = N[log(V*n_Q/N)+5/2]
I've been working on this problem for the past 3 days. I have other papers with different ways of tackling the problem. However, I just cannot get to the answer (change in entropy = 2Nlog(2)).
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Welcome to PF.

Your attached picture of your work is very light and hard to read. Can you upload a better image please?

Also, I will send you a message with tips for posting math equations at PF using LaTeX. That is a much better way to show your work in the future here. :smile:
 

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