Thermaldynamics - Adiabatic system W = delta(U)

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SUMMARY

The discussion focuses on demonstrating the relationship between work (W) and the change in internal energy (\DeltaU) in an adiabatic system. The key equations involved are \DeltaU = W + Q (where Q = 0), and \DeltaU = \frac{1}{2} N k f \Delta T. The user successfully derived W but struggled to connect it to \DeltaU. The solution involves using the ideal gas law (PV = NkT) and the adiabatic process equation (pV^{\gamma-1} = constant), where \gamma = \frac{f+1}{f} to complete the derivation.

PREREQUISITES
  • Understanding of thermodynamic principles, specifically adiabatic processes.
  • Familiarity with the ideal gas law (PV = NkT).
  • Knowledge of internal energy equations (\DeltaU = W + Q).
  • Basic calculus for integration and differentiation in thermodynamics.
NEXT STEPS
  • Study the derivation of the adiabatic process equation (pV^{\gamma-1} = constant).
  • Learn about the relationship between work and internal energy in thermodynamic systems.
  • Explore the implications of degrees of freedom (f) on thermodynamic calculations.
  • Investigate the role of temperature change (\DeltaT) in internal energy calculations.
USEFUL FOR

Students and professionals in physics and engineering, particularly those focusing on thermodynamics and energy systems, will benefit from this discussion.

steve233
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Homework Statement



After integrating the pressure formula of an adiabatic system, I have to show how this is equal to the change in energy. I know that my integral is correct (it was very straight forward), but I'm having trouble showing that it is equal to \DeltaU.

Homework Equations



\DeltaU = W + Q (Q = 0)
PV = NkT
\DeltaU = 1/2 * N * k * f * \DeltaT

Where:
k = 1.381 * 10-23
f = degrees of freedom
\DeltaT = change in temperature

The Attempt at a Solution



W = -PiVi(Vf1-\varphi - Vi1 - \varphi) / 1 - \varphi

Given that, I need to somehow get that to be
\DeltaU = 1/2 * N * k * f * \DeltaT

I managed to reduce W to:

-NkTi((Vf / Vi)1 - \varphi - 1) / 1 - \varphi

But I'm stuck from there.
(Note: \varphi = (f + 2) / f )
Any hints on what to do next would be very helpful.
Thanks
 
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Ideal gas:
pV = NkT
pV^(γ-1) = constant = C for adiabatic proc.
where γ = (f+1)/f

1. write expression for V(T) using both the above eq.
2. get dV = dV(N,k,γ,dT)
3. dW = p(V)dV(N,k,γ,dT). Note that c and V do not appear in this.
4. dU = -dW adiabatic
5. use γ = (f+1)/f and get your answer.
 

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