They used to use uranium glaze to color pottery and other objects

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SUMMARY

The discussion centers on the historical use of uranium glaze in pottery and its implications for radioactivity. Participants clarify that while uranium has a long half-life and emits low levels of alpha radiation, the risk from uranium-glazed pottery is minimal, comparable to living in a brick building. Concerns about other materials, such as cobalt in blue glazes and the dangers of radium in watch dials, are also highlighted. Overall, the conversation emphasizes the need for modern awareness regarding the safety of vintage ceramics and the historical context of radiation exposure.

PREREQUISITES
  • Understanding of alpha radiation and its properties
  • Knowledge of uranium's half-life and decay processes
  • Familiarity with historical uses of radioactive materials in consumer products
  • Awareness of radiation safety protocols and guidelines
NEXT STEPS
  • Research the effects of alpha radiation on human health
  • Explore the historical context of radioactive materials in consumer goods
  • Learn about modern regulations regarding radioactive materials in ceramics
  • Investigate the safety measures for handling radioactive materials in industrial settings
USEFUL FOR

This discussion is beneficial for ceramic artists, historians, safety professionals, and anyone interested in the implications of using radioactive materials in everyday products.

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Before nuclear elements had any practical applications, they were used as an orange coloring glaze for pottery and various other objects.

Please correct me if I'm mistaken, but wouldn't this coloring glaze be highly radioactive?

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Kutt said:
Before nuclear elements had any practical applications, it was used as an orange coloring glaze for pottery and various other objects.

Please correct me if I'm mistaken, but wouldn't this coloring glaze be highly radioactive?

Highly radioactive? No. Uranium has a very long half life, which means it is only slightly active.
 
And U-238's decay is alpha, therefore the very little radiation which's produced won't be able to harm you (unless you inhale parts of the pottery...).
 
Only if it glows in the dark.
 
Up until 30 years ago, the porcelain in false teeth contained uranium salts:

http://hps.org/publicinformation/ate/q2215.html
 
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The radiation dose received from uranium oxide glazed pottery is about the same as the dose received from living or working in a building made of brick or concrete.
 
Indeed some of that old tableware is active.
We used to keep some in the training department at the nuke plant where I worked, for introductory classes in radiation safety. It makes a Geiger counter sound scary and is a good starter for the lecture for it wakes the class up..
But as somebody pointed out it's not very penetrating radiation. So don't worry about your antique china in the display cabinet.

My father in law was a ceramic engineer. He cautioned us about some of the very old blue glazes, said they could leach significant cobalt into your food.

Myself , I use modern tableware because of what's been learned since the 1930's.
Dad's old prewar chemistry book said of element Uranium:
"... sometimes used as colorant in ceramics. The metal has no practical use."

I framed a copy of that page and hung it above my desk in the nuke plant.

old jim
 
Certain types of granite contain many different kinds of nuclear elements and can give off levels of radiation that are many times higher than normal background readings, such as this video shows.



300 cpm and almost 1 msv/h were the highest readings for this granite kitchen sink. The uranium-glazed pottery has nothing on this granite kitchen counter top in terms of radioactivity.
 
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Uranium was used for ceramics and for glassware, to provide color.
I still have some old wine stems with a orange hue from the uranium salts used.
Marie Curie extracted radium from the tailings of the Czech uranium mines. That waste product was cheap enough for her to buy and still held the radioactives she sought.
 
  • #10
Radium used to be painted on watch and clock faces so that they could be read in the dark. The clock and watch factories where this was done became increasingly 'hot' over time.

One time, I saw an old advertisement for a toothpaste which contained a small amount of thorium in its ingredients. Of course, this was pre-Hiroshima and the dangers of radioactivity were not as well known.
 
  • #11
Check this out:
 
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  • #12
SteamKing said:
Radium used to be painted on watch and clock faces so that they could be read in the dark. The clock and watch factories where this was done became increasingly 'hot' over time.

One time, I saw an old advertisement for a toothpaste which contained a small amount of thorium in its ingredients. Of course, this was pre-Hiroshima and the dangers of radioactivity were not as well known.

Before WW2 and the dawn of the "nuclear era" most people were woefully uniformed about the dangers of radiation. Back then, radiation-producing ingredients were frequently included in retail products that would have been outright banned by today's standards.
 
  • #13
Kutt said:
Before WW2 and the dawn of the "nuclear era" most people were woefully uniformed about the dangers of radiation. Back then, radiation-producing ingredients were frequently included in retail products that would have been outright banned by today's standards.

If you look back at this, there were some really nightmarish cases of young women hired to paint radium dials who died from mouth cancers. They were moistening the brushes with their lips to paint the fine lines.
 
  • #14
etudiant said:
If you look back at this, there were some really nightmarish cases of young women hired to paint radium dials who died from mouth cancers. They were moistening the brushes with their lips to paint the fine lines.

Back then, did they teach anything about radiation in elementary and high school science classes? How many people even knew what radiation was?
 
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  • #15
etudiant said:
If you look back at this, there were some really nightmarish cases of young women hired to paint radium dials who died from mouth cancers. They were moistening the brushes with their lips to paint the fine lines.

At the Manhattan project they had a ball of plutonium that they handed to guests. It was radioactive enough to be warm to the touch.
 
  • #16
ImaLooser said:
At the Manhattan project they had a ball of plutonium that they handed to guests. It was radioactive enough to be warm to the touch.

Reportedly they handed one to Stalin, who was suspicious and wanted to be sure that the scientists were not just fooling him. A spontaneously warm metal lump in sunny Moscow was pretty persuasive evidence to him that the researchers were doing something out of the ordinary.
 
  • #17
Kutt said:
Back then, did they teach anything about radiation in elementary and high school science classes? How many people even knew what radiation was?

Not many had any sense of risk. Even the Curies were initially incredibly casual about the radiation exposure. There is another 1920s case of a man who sold radioactive soft drinks as a healthy refresher, sort of a nuclear Gatorade. He eventually also died an ugly death from his elixir, which he had great faith in.
 
  • #18
ImaLooser said:
At the Manhattan project they had a ball of plutonium that they handed to guests. It was radioactive enough to be warm to the touch.

Was this the plutonium warhead core of an atomic bomb?

I'm guessing it was probably radioactive enough to make you very ill within 15-30 minutes of exposure. Plutonium is the most toxic and dangerous substance known to man. I'm sure that the Manhattan project scientists were well aware of this risk.
 
  • #19
Plutonium is the most toxic and dangerous substance known to man. I'm sure that the Manhattan project scientists were well aware of this risk.

That often heard statement is tripe circulated by activists who want to appear impressively knowledgeable.

Manhattan project machinists who fabricated the bomb parts, as well as scientists who worked with the stuff, were monitored for decades after the war.
By 1997 the only unnatural death was from a car crash.

Over the years, there have been a
few other studies on Los Alamos workers
exposed to plutonium, but most of
them are smaller in scope. Published
in 1983, one such study by Voelz et al.
was conducted on 224 males exposed to
plutonium between 1944 and 1974.
Their plutonium deposition was greater
than 0.16 microgram, or 0.01 microcurie.
None of the people involved in this
study developed bone or liver cancer,
and by 1980, the final year of the study,
only one person had died of lung cancer.
This study did not confirm earlier
opinions of some nuclear-industry
critics who predicted a very high risk
for lung cancer at low plutonium doses.
http://www.fas.org/sgp/othergov/doe/lanl/pubs/00818013.pdf

again, please don't spout propaganda as fact.
 
  • #20
Kutt said:
Plutonium is the most toxic and dangerous substance known to man. I'm sure that the Manhattan project scientists were well aware of this risk.

Although I'm not sure about the "most" part of your statement, Plutonium is indeed very toxic and therefore dangerous. Inside the body. Unless I'm mistaken, nuclear warheads are normally stored outside the human body.

As long as the scientists don't start eating the core, there'll nothing happen to their health. Even if they take the thing to bed every night.
 
  • #21
Kutt said:
...
I'm guessing it was probably radioactive enough to make you very ill within 15-30 minutes of exposure. Plutonium is the most toxic and dangerous substance known to man. I'm sure that the Manhattan project scientists were well aware of this risk.

I love when I hear this argument about every two years.

Heres the deal Kutt I'll swallow half of a gram of plutonium and you can have a tenth of gram of cyanide (one fifth of what I just knocked back). I may have several years knocked off of my life expectancy due to a cancer in my GI tract, but I'm going to be alive long enough to goto your funeral, and see my children grow up, and my grandchildren, and who knows if medical science advances enough in the next 50 years my great grandchildren.

To Clancy688 with plutonium in the body I'd be more worried about heavy metal poisoning, or if the plutonium were powdered I'd be worried about inhaling it and having a heavy metal in my lungs, and on a less worry some vector having an alpha emitter in my lungs.
 
  • #22
clancy688 said:
Although I'm not sure about the "most" part of your statement, Plutonium is indeed very toxic and therefore dangerous. Inside the body. Unless I'm mistaken, nuclear warheads are normally stored outside the human body.

As long as the scientists don't start eating the core, there'll nothing happen to their health. Even if they take the thing to bed every night.

Also, I believe nuclear cores are usually electroplated with a layer of stable, non-corroding and non-toxic metal.
 
  • #23
Much like holding a handful of fuel pellets, I'm assuming that holding a ball of raw nuclear material that is radioactive enough to be warm to the touch is bad for ones health.

This is why human handling of nuclear fuel (such as at a fuel processing plant) is done through very thick glass and with lead-insulated gloves.
 
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  • #24
Kutt said:
I'm assuming that holding a ball of raw nuclear material that is radioactive enough to be warm to the touch is bad for ones health.

You have to differ.

Plutonium is alpha decay. Alpha radiation is very powerful, but at the same time has only very little penetration ability. So little that it is stopped by the uppermost boundary of human skin - which consists mostly of dead cells.

Therefore you don't need any lead glass or special gloves when handling plutonium since its radiation can't penetrate your body deep enough to do damage.

It's an entirely different matter when this stuff is inside your body, though. There was a guy called Litwinenko. Google him. He was poisened with Polonium-210, which emits alpha radiation just like Plutonium.
 
  • #25
clancy688 said:
You have to differ.

Plutonium is alpha decay. Alpha radiation is very powerful, but at the same time has only very little penetration ability. So little that it is stopped by the uppermost boundary of human skin - which consists mostly of dead cells.

Therefore you don't need any lead glass or special gloves when handling plutonium since its radiation can't penetrate your body deep enough to do damage.

It's an entirely different matter when this stuff is inside your body, though. There was a guy called Litwinenko. Google him. He was poisened with Polonium-210, which emits alpha radiation just like Plutonium.

Now let's be fair here. Yes both Polonium 210 and Plutonium 239 are alpha emitters. However Polonium is an alpha fire hose, it has an approximate half life of 138 days. Where as Plutonium is more like a dripping faucet of alpha emitters, 24k years.

And yes half life dose matter, the shorter the half life (hours, days, three digit years) elements are going to be more dangerous due to a much more energetic life.
 
  • #26
Kutt said:
Much like holding a handful of fuel pellets, I'm assuming that holding a ball of raw nuclear material that is radioactive enough to be warm to the touch is bad for ones health.

This is why human handling of nuclear fuel (such as at a fuel processing plant) is done through very thick glass and with lead-insulated gloves.

Kutt, you're just a wealth of misinformation.

I toured a fuel pelletizing plant south of St Louis.
The fuel comes in as gas in cylinders and leaves as small green pellets that look like rabbit food.
The automated machinery is reminiscent of cigarette manufacturing equipment.
You can stand right beside it and watch the pellets go by on little conveyor belts.
Nice ladies carry trays of it where it needs to go, wearing thin gloves just like in a cafeteria.
As visitors we were not allowed to handle it, it was after all 'snm' and you don't want to get fingerprints on it.

The equipment you describe is for handling high level radioactive waste not new fuel.

Fuel is shipped to the power plant on flatbed trucks driven by regular truck drivers over regular highways. They stop for lunch at regular truck stops.

When we take it from the truck we wear gloves of thin cotton, again so as to not get fingerprints on it.
New fuel is barely (if at all) radioactive and I have stood amidst tons of it in our new fuel storage room.

Please spend some time educating yourself.
And quit trying to scare people.

old jim
 
  • #27
Kutt said:
This is why human handling of nuclear fuel (such as at a fuel processing plant) is done through very thick glass and with lead-insulated gloves.
Um - no. I've handled fuel pellets at a number of fabrication plants. One uses a thin glove, latex or alternative. At a reprocessing plant, the MOX or reprocessed fuel is handled remotely, certainly with operators shielded.

jim hardy said:
I toured a fuel pelletizing plant south of St Louis.
I've been there a couple of times.

UF6 is a solid at room/transportation temperature. The container is heated to about 125°C in a steam chest. The gas is hydrolyzed in a solution (wet process) or steam (dry process).
 
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  • #28
jim hardy said:
I toured a fuel pelletizing plant south of St Louis.

Jim and Astronuc can the public still tour this facility, or is it like all NPPs after Sep 11. It sounds like a really cool place to go see, how would you rate it compared to EBR 1?
 
  • #29
Astronuc said:
...

I've been there a couple of times.

UF6 is a solid at room/transportation temperature. The container is heated to about 125°C in a steam chest. The gas is hydrolyzed in a solution (wet process) or steam (dry process).

Thanks - if I ever knew that i'd forgotten it...
sorry for the misinformation. I should have checked before asserting.

250px-Uranium_hexafluoride_phase_diagram.gif

http://en.wikipedia.org/wiki/Uranium_hexafluoride
 
  • #30
Argentum Vulpes said:
Jim and Astronuc can the public still tour this facility, or is it like all NPPs after Sep 11. It sounds like a really cool place to go see, how would you rate it compared to EBR 1?
It was shutdown more than 10 years ago (2001), and the site decommissioned as far as I know. The company was merged into another larger company as part of an industry consolidation.
 
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