Time Evolution After Sudden Potential Change

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SUMMARY

The discussion focuses on the time evolution of a particle initially confined in an infinite potential well, described by the potential function \( V(x) = 0 \) for \( -\frac{a}{2} \leq x \leq \frac{a}{2} \) and infinite elsewhere. After the potential is removed, the participant has derived the initial wavefunction in position space as \( \psi(x, t=0) = \sqrt{\frac{2}{a}} \sin(\frac{\pi x}{a} + \frac{\pi}{2}) \) and its corresponding momentum space wavefunction. The key challenge is to apply the Hamiltonian operator for a free particle to evolve the wavefunction over time, utilizing the relation \( |\psi(t)\rangle = e^{-iHt / \hbar} |\psi(0)\rangle \) to compute \( \psi(x,t) \).

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Homework Statement


A particle in an infinite potential well ##V(x) = 0, -\frac{a}{2} \leq x \leq \frac{a}{2}##, and infinite elsewhere is in it's ground state. Subsequently, the potential is removed and the particle is free to move.

How does the probability distribution in x and p change immediately after the walls are removed?

Homework Equations

The Attempt at a Solution


[/B]
I have found and normalised my wavefunction in position space ##\psi (x, t=0) = \sqrt{\frac{2}{a}} \sin(\frac{\pi x}{a} + \frac{\pi}{2})##

I have taken the Fourier transform of this wavefunction to find the wavefunction in momentum space ##\psi (p, t=0) = \frac{2 \hbar^{\frac{3}{2}} \sqrt{\pi}}{\sqrt{\frac{1}{a}} (\hbar^2 \pi^2 - a^2 p^2)} \cos(\frac{pa}{2 \hbar})##

with these, i can calculate the probability density in x and p at t=0, but i am unsure of how to proceed once the potential has been removed.

From reading the wikipedia page here: https://en.wikipedia.org/wiki/Hamiltonian_(quantum_mechanics)#Free_particle

I think I might need to make use of this relation: ##|\psi(t)\rangle = e^{-iHt / \hbar} |\psi(0)\rangle##, where I use the hamiltonian of the free particle to compute how my initial wavefunction evolves.

I am not familiar with Dirac notation however - Is that equivalent to the hamiltonian acting on the wavefunction in the argument of the exponential?

something like ##\psi (x,t) = e^{-iH \psi(x, t=0) t / \hbar}##

Thanks for any help you can give!
 
Last edited:
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I am really confused.

Do I just need to make use of ##\hat{H} \psi (x,0) = E \psi (x,0)##, and ##\psi (x,t) = e^{-iEt/\hbar} \psi (x,0)##?

Using the hamiltonian for a free particle
 

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