Total angular momentum quantum number

In summary, the total angular momentum quantum number J for an electron configuration of 1s^2 2s^2 2p^2 3p^1 is 7/2. This is calculated by adding the individual angular momentum values for each state, taking into account the spin and orbital angular momentum of the electrons. The total spin for the s shell is 0, while the p shell has a total orbital angular momentum of 2 and a spin of 1/2. Therefore, the total angular momentum is 2+1+1/2=7/2.
  • #1
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lets say there is an electron configuraiton of [tex]1s^2 2s^2 2p^2 3p^1[/tex]

I want to find the total angular momentum quantum number, J=L+S

considering the n=1 state, there are two electrons, in the s shell which means one is spin 1/2 and the other is spin -1/2 giving a total spin of 0. The s shell has no angular momentum so L=0.

considering n=2 state, there are two electrons in the s shell which again gives us 0 total angular momentum. If we went to the p shell, there are 2 electrons in the p shell, each having L=1, so we add them together to get L=2. The two electrons do not contribute spin since their net sum is zero, S=1/2-1/2=0.

considering the n=3 state, there is 1 electron in the p shell, which means S=1/2 and L=1

J is the sum of L and S, so the total angular momentum should be J=L+S=2+1+1/2=7/2

Is this correct?
 
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  • #2
any ideas?
 
  • #3


Yes, your calculation of the total angular momentum quantum number, J, is correct. The total angular momentum quantum number is a combination of the orbital angular momentum quantum number, L, and the spin quantum number, S, and is represented by the letter J. In this case, the electron configuration of 1s^2 2s^2 2p^2 3p^1 has a total angular momentum of 7/2. This information can be useful in understanding the properties and behavior of atoms and molecules.
 

1. What is the significance of the total angular momentum quantum number?

The total angular momentum quantum number, also known as the quantum number l, describes the magnitude of the angular momentum of an electron in an atom. It determines the shape of the electron's orbital and plays a crucial role in the arrangement of electrons around the nucleus.

2. How is the total angular momentum quantum number related to the principal quantum number?

The total angular momentum quantum number is related to the principal quantum number (n) through the equation l = 0, 1, 2,..., n-1. This means that for each value of n, there can be a maximum of n possible values for l, which correspond to the different orbital shapes.

3. What is the range of values for the total angular momentum quantum number?

The total angular momentum quantum number can take on non-negative integer values from 0 to n-1, where n is the principal quantum number. This means that for a given value of n, there can be a maximum of n possible values for l.

4. How does the total angular momentum quantum number affect the energy of an electron?

The total angular momentum quantum number does not directly affect the energy of an electron. However, it does influence the energy levels and sublevels available to the electron, which in turn affects the electron's energy. The higher the value of l, the higher the energy of the electron in that orbital.

5. Can the total angular momentum quantum number have a negative value?

No, the total angular momentum quantum number cannot have a negative value. It is always a non-negative integer ranging from 0 to n-1, where n is the principal quantum number. This is because it represents the magnitude of the angular momentum, which cannot be negative.

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