Total spin quantum number of helium atom with 2 electrons in first shell

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Homework Help Overview

The discussion revolves around determining the total spin quantum number of a helium atom with two electrons in the first shell (1s). Participants are exploring the implications of the Pauli exclusion principle and the nature of electron spins in quantum mechanics.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants discuss the implications of the Pauli exclusion principle on electron spins and question whether the total spin of the atom can be zero. There is also a distinction made between the total electronic spin and the overall atomic spin, prompting inquiries about the nature of spin states for two electrons.

Discussion Status

Some participants have raised misconceptions regarding the calculation of the total spin, leading to a deeper examination of the addition of angular momentum in quantum mechanics. Guidance has been offered to revisit fundamental concepts, indicating a productive direction in the discussion.

Contextual Notes

There is a noted lack of clarity regarding the distinction between the total electronic spin and the overall atomic spin, as well as the role of nuclear spin in the context of the problem. Participants are also questioning the relevance of the z-component of spin in their calculations.

umagongdi
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Homework Statement



A helium atom had two electrons in the first shell (1s). Explain, withour detailed derivation, what the value of the total spin quantum number is.

Homework Equations



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The Attempt at a Solution



Since the 2 electrons are in the first (1s) shell they must have opposite spins, +1/2, and -1/2 due to pauli exclusion principle. The total spin must be their sum +1/2-1/2=0. Therefore the atom spin is 0? Can atoms have spin 0?
 
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A couple of misconceptions:

1) That's not the spin of the atom. The spin of the atom is the sum of the electronic spin, the nuclear spin, and the orbital angular momentum. (There's no reason the spin of an atom can't be 0.)

2) You've shown that the z-component of the total electronic spin is 0. You haven't shown that the total spin is 0. It's possible, for instance, that the electrons are in the S=1, mS=0 state.

I'm guessing the problem isn't asking about the atom's spin but just the total electronic spin. When you have two spin-1/2 particles, their spins can combine to form an S=0 or S=1 state. You need to explain why one of them is not allowed.
 
vela said:
A couple of misconceptions:

1) That's not the spin of the atom. The spin of the atom is the sum of the electronic spin, the nuclear spin, and the orbital angular momentum. (There's no reason the spin of an atom can't be 0.)

2) You've shown that the z-component of the total electronic spin is 0. You haven't shown that the total spin is 0. It's possible, for instance, that the electrons are in the S=1, mS=0 state.

I'm guessing the problem isn't asking about the atom's spin but just the total electronic spin. When you have two spin-1/2 particles, their spins can combine to form an S=0 or S=1 state. You need to explain why one of them is not allowed.

I asked the proffesor and he said the same, that the answer was just for the z-axis, he didn't explain. Why is this for the z-axis? Is the total spin just the sum of all the spins? But we don't know the nuclear spin etc?
 
You need to go back and review the addition of angular momentum in quantum mechanics. This is a fundamental topic in quantum mechanics that you need to know. In particular, you should be able to apply the concepts to two spin-1/2 particles to find their total angular momentum.
 
thanks
 

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