Uncertainty of an electron in a core

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Discussion Overview

The discussion revolves around the uncertainty of an electron confined in a spherical box, specifically addressing the position uncertainty and its implications for calculating momentum and kinetic energy uncertainties. Participants explore theoretical aspects and potential approaches to the problem.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Homework-related
  • Mathematical reasoning

Main Points Raised

  • One participant questions whether the position uncertainty should be taken as ##\Delta x = r## or ##\Delta x = 2r##, indicating the need for clarity in calculations of momentum and kinetic energy uncertainties.
  • Another participant suggests that both values could be used for rough approximations, but emphasizes that a proper calculation would require a more complex approach.
  • Some participants clarify that the rest energy is constant and does not contribute to uncertainty, while kinetic energy uncertainty is derived from momentum uncertainty.
  • There is a discussion about the implications of the professor's instructions regarding whether to calculate an 'order of magnitude' or the exact uncertainty, which affects the choice between ##\Delta x = r## and ##\Delta x = 2r##.
  • Concerns are raised about the potential for error if the professor's expectations are not clearly defined, particularly regarding the lower bound of uncertainty in momentum.
  • One participant expresses frustration over a calculation that was off by a factor of ##1/2## after significant effort, seeking feedback on their derivation process.

Areas of Agreement / Disagreement

Participants express uncertainty regarding the correct choice of position uncertainty and whether it affects the calculations. There is no consensus on the implications of the professor's instructions, leading to multiple competing views on how to approach the problem.

Contextual Notes

Participants note that the discussion may depend on specific definitions and assumptions about the problem, particularly regarding the treatment of uncertainties and the context of the professor's instructions.

71GA
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Lets say we put an electron in a box (spherical) which has a radius ##r##. I want to know if position uncertainty ##\Delta x = r## or is it ##\Delta x = 2r##?

I need to know this to corectly calculate 1st the momentum uncertainty ##\Delta p=\frac{\hbar}{2\Delta x}## and 2nd that kinetic energy uncertainty ##\Delta E_k## using the Lorentz invariant like this:

\begin{align}
\Delta E^2 &= \Delta p^2 c^2 + {E_0}^2\\
\Delta E &= \sqrt{\Delta p^2 c^2 + {E_0}^2}\\
\Delta E_k + E_0 &= \sqrt{\Delta p^2 c^2 + {E_0}^2}\\
\Delta E_k &= \sqrt{\Delta p^2 c^2 + {E_0}^2} - E_0\\
\end{align}

Furthermore. Can anyone elce confirm that this is the proper way to get the kinetic energy uncertainty ##\Delta E_k##. Is it ok that uncertainty for full energy ##\Delta E## all comes from the uncertainty in kinetic energy ##\Delta E_k## and none from rest energy (infront of which i wrote no deltas) ##E_0##?
 
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Is this homework? You can use both, it does not matter for a rough approximation. A proper calculation would give the correct prefactor, but that is way more complicated.

ΔE is the minimal kinetic energy (again, neglecting small prefactors), the rest energy is constant and cannot have an uncertainty.
 
mfb said:
Is this homework?

I have been solving a homework yes, but i didn't know if i have to take ##\Delta x = r## or ##\Delta x = 2r##. But the question is theoretical. How do you mean i can use both? I still don't understand...
 
mfb means that if you were only asked to calculate the 'order of magnitude' of the uncertainty, then the teacher will say you are correct if you write [itex]\Delta x=r[/itex] or [itex]\Delta x = 2r[/itex]. (This is quite common for these types of questions). But if your teacher did not say 'order of magnitude', then assume he/she will care about which one you use.

Now, assuming you are not meant to do any Fourier transforms, then you are not supposed to calculate the exact uncertainty in momentum. So, as you say, you have the choice between [itex]\Delta x=r[/itex] or [itex]\Delta x = 2r[/itex]. Without doing any extra calculations, can you guarantee that [itex]\Delta x<2r[/itex]? And keep in mind that you are trying to come up with a lower bound of the uncertainty. This should determine which one you choose.

edit: Actually, I don't know if you are looking for a lower bound on uncertainty in momentum (see post 7)
 
Last edited:
BruceW said:
mfb means that if you were only asked to calculate the 'order of magnitude' of the uncertainty, then the teacher will say you are correct if you write [itex]\Delta x=r[/itex] or [itex]\Delta x = 2r[/itex]. (This is quite common for these types of questions). But if your teacher did not say 'order of magnitude', then assume he/she will care about which one you use.

Now, assuming you are not meant to do any Fourier transforms, then you are not supposed to calculate the exact uncertainty in momentum. So, as you say, you have the choice between [itex]\Delta x=r[/itex] or [itex]\Delta x = 2r[/itex]. Without doing any extra calculations, can you guarantee that [itex]\Delta x<2r[/itex]? And keep in mind that you are trying to come up with a lower bound of the uncertainty. This should determine which one you choose.

So i can't go wrong if i choose ##\Delta x = r## or ##\Delta x = 2r## unless my professor states which one to use. This is a good news indeed. I only used Fourier transform when dealing with Gauss to derive ##\Delta x \Delta p = \frac{\hbar}{2}##. Well i got ##\Delta x \Delta p = \hbar## which i couldn't explain after putting a week of effort in it... What a waste...
 
71GA said:
So i can't go wrong if i choose ##\Delta x = r## or ##\Delta x = 2r## unless my professor states which one to use. This is a good news indeed.
ah, be careful though. I would say ONLY if your professor stated 'order-of-magnitude', then you can't go wrong with either. If your professor did not say this, then I would say most likely you can go wrong, depending on which one you choose.

71GA said:
I only used Fourier transform when dealing with Gauss to derive ##\Delta x \Delta p = \frac{\hbar}{2}##. Well i got ##\Delta x \Delta p = \hbar## which i couldn't explain after putting a week of effort in it... What a waste...
Ah, I know that heartbreaking feeling, when you get to the end of a long calculation and it is off by some factor.
 
BruceW said:
ah, be careful though. I would say ONLY if your professor stated 'order-of-magnitude', then you can't go wrong with either. If your professor did not say this, then I would say most likely you can go wrong, depending on which one you choose.
Actually, uh... This depends was the problem to find a lower bound for the uncertainty in momentum, or just to find the uncertainty in momentum. Because if it was just 'find uncertainty in momentum', then yeah most likely you can't go wrong if you choose r or 2r as uncertainty in x.
 
BruceW said:
Ah, I know that heartbreaking feeling, when you get to the end of a long calculation and it is off by some factor.

Well this are the two pages that i have written to derive the uncertainty but missed it for a factor of ##1/2## (it is in the attachment). Maybee you could spot my mistake =)
 

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