Uncovering the Mystery of Hydrogen: Surprising Observations from Electrolysis

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Discussion Overview

The discussion revolves around observations made during the electrolysis of water to produce hydrogen gas. Participants explore the characteristics of the gas produced, its combustion properties, and the implications of these observations in the context of chemical reactions and safety considerations.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • One participant describes observing a gas produced during electrolysis that extinguishes a flame, initially suspecting it to be carbon dioxide, but later concludes it is hydrogen due to explosive combustion when ignited with soap bubbles.
  • Another participant suggests that the observed combustion is likely due to hydrogen gas, noting that hydrogen can combust violently and that impurities might contribute to visible flames.
  • A different participant expresses excitement about the potential of hydrogen torches, mentioning that flame temperature can vary based on the material being burned.
  • One participant explains that hydrogen is produced at the cathode during electrolysis and that the gas generated at the anode depends on the electrolyte used, such as chlorine gas from NaCl.
  • Concerns are raised about safety, with a warning that larger explosions can be dangerous and that caution is necessary when handling hydrogen gas.

Areas of Agreement / Disagreement

Participants generally agree on the explosive nature of hydrogen gas and the conditions under which it is produced. However, there are varying interpretations regarding the visibility of the flame and the role of impurities, indicating some unresolved aspects of the discussion.

Contextual Notes

Participants mention the influence of different electrolytes on the gases produced and the potential for varying combustion characteristics, but these factors remain complex and not fully resolved in the discussion.

Who May Find This Useful

This discussion may be of interest to individuals exploring electrolysis, combustion chemistry, or safety practices in experimental setups involving hydrogen gas.

atom888
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hi all,

I was doing electrolysis to produce hydrogen. I start getting a gas that is so mysterious to my science knowledge. When i put fire into it, it eat up the flame and put out the lighter. AT first I thought that must be carbon-dioxide (fire extinguisher reagent). Then i put some soap into the surface of the solution and collect that gas in bubbles. When i put fire in it, it explode. I am convinced that it is hydrogen. This contradict to science that hydrogen is flamable. I read a government physics document said that the reaction of hydrogen and oxygen is a colorless flame. Then there must be a present of something that make hydrogen combust into a real visible flame in the air... It seems like hydrogen will be friendly to friendly element(thus produce so low temperature,colorless flame) and aggressive with aggressive element (metal) (produce a high temperature, visible flame) .
 
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It's likely that the major reaction you were seeing was the combustion of hydrogen gas. Hydrogen combusts pretty violently, often explosively (which is why balloons are no longer made of hydrogen). While it is true that pure oxygen-hydrogen flames emit light in the ultraviolet, impurities from the soap or water could have provided some trace elements which would be visible.

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It's incredible. I've seen video that hydrogen torch can melt anything. It also mysterious that the flame temperature get higher depends on the material. A normal torch cannot do that. I'm so excited to make hydrogen tomorrow. Hopefully at a rate to create a mini torch to melt stuff.
 
Hydrogen gas will be produced at the cathode (negative terminal).
Noticeable more Hydrogen bubbles will be produced compared to the other gas which is generated at the anode (+).

What that other gas is, the one generated at the anode, will depend on what electrolyte you are using. For example, if you have Chloride ions present in your solution (possibly from NaCl being your electrolyte) then you will get some Chlorine gas generated as opposed to only Oxygen.

Hydrogen will burn extremely rapidly in air, and even more so if it is pre-mixed with an oxidizing gas (for example, Oxygen gas or Chlorine gas). It might be that igniting the Hydrogen bubbles is blowing out your lighter’s flame.

When you trap Hydrogen in bubbles and ignite them you should hear a popping sound as they burn. If they are very small bubbles (like a foam, but not in that high of a concentration) then you might not heat so much, but if the bubbles are large then the popping sound can be surprisingly loud.
 
Just don't forget to be careful, if you don't want to land in the hospital. These explosions - when they get larger - can be quite dangerous.
 

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