Understanding Alcohol Ignition: The Science and Percentage Explained

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SUMMARY

The ignition of alcohol, specifically ethanol, is influenced by its concentration in water. Solutions containing less than 20% ethanol (40 proof) do not ignite at room temperature, while concentrations above this threshold can ignite depending on specific conditions. The vapor pressure of ethanol does not increase linearly with concentration, complicating the determination of the minimum flammable concentration. The "proof" scale indicates that 100 proof corresponds to 50% ethanol, which is approximately the minimum flammable concentration at room temperature.

PREREQUISITES
  • Understanding of ethanol and its properties
  • Familiarity with the concept of vapor pressure
  • Knowledge of the alcohol proof scale
  • Basic principles of combustion and ignition
NEXT STEPS
  • Research the flash points of various ethanol-water solutions
  • Study the relationship between vapor pressure and flammability limits
  • Explore the chemistry behind combustion and ignition temperatures
  • Learn about the effects of water content on alcohol ignition
USEFUL FOR

Chemists, safety professionals, and anyone interested in the properties of alcohol and its ignition characteristics.

shimun
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1. Can anyone explain in basic way, when alcohol begins to burn from external fire touch, precisely in procentage. as we kown vodka 40% of alcohol don't fire up.
2. Can anyone answer me in basic way, why is what ?
 
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shimun said:
2. Can anyone answer me in basic way, why is what ?

I don't get to understand what you want to know...
 
shimun said:
as we kown vodka 40% of alcohol don't fire up.

Sure it does, you just have to know how to ignite it.

marcin_blue.jpg


I doubt you will get a single number as a lot depends on how you define ignition conditions.
 
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It's depending of the % of water and the % of alchohol I think. :smile:
 
The concentration of ethanol in the water has to be high enough for its vapor pressure to be within flammability limits at that temperature. The vapor pressure does not increase linearly from zero to the value of pure ethanol when the alcohol percentage is increased, so it's difficult to calculate the minimum concentration without having experimental data, but the "proof" scale of alcohol percentage, where 100 proof is equal to 50% vol. of ethanol is based on the approximate minimum flammable concentration at room temperature.
 

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