Understanding Electrolysis: How Do Ions and Current Flow?

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    Electrolysis Work
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Discussion Overview

The discussion focuses on the process of electrolysis, specifically how ions and current flow within an electrolytic cell. Participants explore the roles of electrodes, the movement of ions in an ionic solution, and the generation of current through the system.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant expresses confusion about electrolysis and requests a detailed explanation of how current flows and how electrodes acquire their charges.
  • Another participant explains that a battery is used to create a positive and negative electrode, generating an electric field that influences the movement of ions in opposite directions.
  • A third participant describes the flow of electrons and the roles of cations and anions in the electrolysis process, noting how they interact with the electrodes and the battery terminals.
  • One participant acknowledges improved understanding of the electrolysis process after the explanations provided.

Areas of Agreement / Disagreement

Participants generally agree on the basic mechanism of electrolysis, including the roles of electrodes and the movement of ions. However, there are nuances in the explanations regarding the direction of current flow and the definitions of current that remain unclarified.

Contextual Notes

Some assumptions about the definitions of current and the conventions used in measuring it are not fully resolved. The discussion also does not clarify the specific details of how the electric field is established or the exact nature of the interactions between ions and electrodes.

Who May Find This Useful

Students beginning their studies in physics, particularly those interested in electrolysis and the behavior of ions in electric fields.

Deep_Thinker97
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Right, I've started physics a level and electrolysis has always confused me since gcse, so please be very detailed!
This is what I know, (or assume) so far: there is a cell; that cell is connected to two electrodes; one is positive, the other is negative. The electrodes are placed in an ionic solution, where positive ions move to the negative electrode and negative ions move to the positive electrode.
I don't understand how current moves throughout the process. How do the electrodes get their charges in the first place? And overall, what direction does the current flow if the ions in the solution move in both directions!
Please help me!
 
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You attach the electrodes to a battery which makes one negative and one positive. An electric field will be produced between the two electrodes, and charges in an electric field experience an electric force. The positive and negative ions experience forces in the opposite direction.

The current takes the sign of the charge as well as its direction into account. A positive charge moving right to left gives the same current as a negative charge moving left to right. When the positive and negative ions move in opposite directions, they both add constructively to the total current.

1 amp of negative charge moving one direction + 1 amp of positive charge going the opposite direction = 2 amps total.

Whichever way you define this total current is a matter of convention, and I've forgotten which way humans conventionally decided on.
 
A battery is connected to two electrodes put into a solution.The positive electrode is in the side of positive terminal of battery and vise versa.(Because the electrons in the Anode(Positive electrode) moves towards the positive terminal of battery making the electrode positively charges and vise versa).The cations move toward the cathode(negative electrode) and gets discharged,so,gaining electrons.The Anions(negative ions)moves toward the anode(positive electrode)giving electrons to the positive electrode which travels to the positive terminal,thus electrons flow through the circuit.
 
Thank you, i understand the process more now
 

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