The space of Linear transformations L(U,V), where U and V are finite dimensional linear spaces, with dimensions m and n, is itself a linear space with dimension mn; its "standard" basis is the set of matrices Ekl, defined by:
[tex][Ekl]_{ij}[/tex] = [tex]\delta_{kilj}[/tex]
These basis are called "standard", because they are built using only the unit (1) of the scalar field; therefore, given a representation of the vector relative to this basis, its coordinates are, in a sense, immediate.
Regarding the general question, every vector space, finite or infinite dimensional, has indeed a basis of this type, called an Hamel basis, and also because they are completely classified by their dimension (vector spaces with the same dimension are isomorphic); of course, in infinite dimensional spaces, the Hamel basis is uncomputable (and unenumerable); in finite dimensions, it coincides with the usual canonical (or "standard basis").