Dadface
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haruspex said:No. At the point of detachment the net acceleration is vertical. If you break that into radial and tangential components, the tangential component is nonzero but is missing from your equation.
This wrong equation led you to the erroneous 0.91 answer and thus to a relatively modest 2.7 for the coefficient of friction. With the correct ≈0.85 answer the coefficient of friction becomes huge (in fact, infinite).
Since you do not care about the tangential acceleration, simpler to resolve gravity into tangential and radial components: mg sin(α) = marad.
I am considering the instant when contact forces reduce to zero. At an infinitesimally small time before that instant contact forces will be infinitely small and the majority of the centripetal force will be provided by the inward component of the weight. At an infinitely small time after that instant detachment will be complete and the initial free flight path of of the object will be in a direction tangential to the circle at the point of release.