Volume of Oxygen Liberated from Hydrogen Peroxide

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SUMMARY

The discussion centers on calculating the volume of oxygen liberated from a 1L solution of 3% hydrogen peroxide (H2O2) using the decomposition reaction 2H2O2(aq) → 2H2O(l) + O2(g). The solution involves determining the mass of H2O2 in the solution, converting it to moles, and applying the stoichiometric ratio to find the volume of oxygen produced at standard temperature and pressure (STP). The final calculation yields approximately 9.88L of oxygen, confirming that 10L is a reasonable estimate.

PREREQUISITES
  • Understanding of stoichiometry and mole calculations
  • Familiarity with the concept of molar mass (e.g., H2O2: 34g/mol)
  • Knowledge of gas laws, specifically the volume of gas at STP (22.4L/mol)
  • Basic understanding of solution concentration (e.g., 3% solution as 3g/100mL)
NEXT STEPS
  • Study the decomposition reactions of hydrogen peroxide in detail
  • Learn about calculating gas volumes from chemical reactions using stoichiometry
  • Explore the properties and applications of hydrogen peroxide in various concentrations
  • Investigate the implications of gas laws in real-world chemical processes
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Chemistry students, educators, and professionals involved in chemical analysis or laboratory work, particularly those focusing on reaction stoichiometry and gas calculations.

brbrett
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Homework Statement


Hydrogen peroxide breaks down easily to give water and oxygen as follows:
2H2O2(aq)----> 2H2O2(l) + O2(g)
Bottles of hydrogen peroxide are sometimes labelled as 10 volume as well as 3%. This means the volume of oxygen that can be liberated is 10 times the volume of the solution. Remembering that 1 mol at STP of any gas occupies 22.4L, calculate the volume of oxygen at STP that could be produced from 1L of a 3% solution. Is 10L a good approximation to your answer?

Homework Equations


2H2O2(aq)----> 2H2O2(l) + O2(g)
3% refers to 3g/100mL
Mole equations and density

The Attempt at a Solution


Knowing that I have a 1L solution, I make 3g/100ml into 30g/L.
Working from there, I divide 30g H2O2 by the molar mass, 34g/mol, to find moles of H2O2.
The equation states there is a 2:1 ratio between hydrogen peroxide and oxygen, so I divide the moles by 2.
I then multiply the moles of Oxygen by 22.4 to find the volume, which I find is 9.88L (in line with the question's estimate of 10L as well).

I quite literally just thought of this possible solution when I was posting this for help. I'm uncertain as to whether or not I went about this properly, particularly in finding the grams of H2O2 in the 1L solution.

As always, appreciate any help on the matter.
 
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brbrett said:
2H2O2(aq)----> 2H2O2(l) + O2(g)

Beware - you are not producing H2O2 but H2O (but I suppose it just a typo).

Knowing that I have a 1L solution, I make 3g/100ml into 30g/L.
Working from there, I divide 30g H2O2 by the molar mass, 34g/mol, to find moles of H2O2.
The equation states there is a 2:1 ratio between hydrogen peroxide and oxygen, so I divide the moles by 2.
I then multiply the moles of Oxygen by 22.4 to find the volume, which I find is 9.88L (in line with the question's estimate of 10L as well).

Looks OK.
 
Yes. I assume I copied it down wrong, but I left it like that just in case.
Thanks for the help!
 

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