What Causes Refraction in Different Media?

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When waves change velocity, it is necessary for the wave direction (the wave-vector) to change direction as they refract across a boundary; so as to preserve field continuity across the boundary.

Microscopically, refraction occurs because atoms act as driven oscillators that impart a phase shift on the incident wave - ultimately causing the (group velocity of the) wave to slow.

Claude.
 
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Claude Bile said:
When waves change velocity, it is necessary for the wave direction (the wave-vector) to change direction as they refract across a boundary; so as to preserve field continuity across the boundary.

Microscopically, refraction occurs because atoms act as driven oscillators that impart a phase shift on the incident wave - ultimately causing the (group velocity of the) wave to slow.

Claude.

Yes: atoms, molecules, ions and plain free electrons, all in different circumstances and for different frequencies of EM.
A good non-QM description is always best when possible, I always say.