What Determines the Valence of Transition Metals?

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SUMMARY

Transition metals typically exhibit two valence electrons in their normal state, as evidenced by their electron configurations. The discussion highlights that the d electrons are considered valence electrons and play a crucial role in bonding. The varying valences of transition metals arise from the ability of d electrons to participate in chemical reactions, leading to multiple oxidation states. The electron configurations of specific transition metals, such as Scandium (Sc) and Titanium (Ti), illustrate the filling order of the 3d and 4s orbitals, confirming the significance of these electrons in determining valence.

PREREQUISITES
  • Understanding of electron configurations
  • Familiarity with transition metals and their properties
  • Knowledge of oxidation states and valence electrons
  • Basic principles of chemical bonding
NEXT STEPS
  • Research the electron configuration of other transition metals
  • Study the concept of oxidation states in transition metals
  • Explore the role of d electrons in chemical bonding
  • Learn about the significance of the periodic table columns 1B-8B
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Chemistry students, educators, and professionals interested in the properties and behaviors of transition metals in chemical reactions.

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Judging from the electron configurations, it appears to me that all transition metals in their normal state have 2 valence electrons. If it isn't, what are the valences of the transition metals, why can they have many different valences, and what are the 1B-8B columns for?

Number of electrons in each energy shell:
Ar : 2, 8, 8
K : 2, 8, 8, 1
Ca : 2, 8, 8 , 2
(Transition Metals)
Sc : 2, 8, 9 , 2
Ti : 2, 8, 10, 2
V : 2, 8, 11, 2
Cr : 2, 8, 12, 2
::
::
::
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Zn : 2, 8, 18, 2
Ga : 2, 8, 18, 3---------and so on.
 
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That's because the 3d electrons are listed before the 4s. The 4s orbital gets filled first, hence Ca is 4s2, and then the 3d orbitals (the 4s being completely filled), hence Sc is 3d14s2, and so on.

The d electrons are most definitely valence electrons and participate in bonding.
 

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