What elements can be represented by the letter R in organic chemical structures?

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SUMMARY

The letter "R" in organic chemical structures represents an unspecified group or molecule, which can include alkyl groups or groups containing heteroatoms. In the context of ketones, "R" can denote various groups, such as methyl or ethyl, indicating that ketones can have diverse substituents attached to the carbonyl carbon (O=C). Aldehydes, on the other hand, have specific structural requirements where the carbon must be bonded to at least one hydrogen atom. Understanding these distinctions is crucial for accurately interpreting organic structures.

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  • Knowledge of ketones and aldehydes
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MycelliumMan
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Organic element symbol "R"

I keep hearing different things about what exactly the letter R represents in organic chemical structures. Does the R always represent an alkyl group or can it represent groups with heteroatoms? For example
http://upload.wikimedia.org/wikipedia/commons/thumb/3/3a/Aldehyde2.png/60px-Aldehyde2.png
http://upload.wikimedia.org/wikipedia/commons/thumb/4/48/Ketone-general.png/60px-Ketone-general.png
there's the structure of an aldehyde and a ketone. Can I safely assume that the R's attached of the ketone will be Carbon atoms and will be attached to other C or H atoms. In other words will a ketone always have alkyl groups attached to its O=C or can a ketone have any elements in it?
 
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The 'R' just means an unspecified group/molecule that's attached. You also might see 'X' to denote a halogen (fluorine, chlorine, bromine, iodine, etc.) when it's not important to specify which.

So a aldehyde is a carbon with a double-bonded oxygen and hydrogen on it. What the 'R' stands for there could be anything, as simple as a methyl group, or some crazily complex organic molecule.

Note that the ketone specifically notes it can have two different groups attached to it. So it might have a methyl on one side and an amino on the other side, or an ethyl and propyl, or whatever.
 
MycelliumMan said:
I keep hearing different things about what exactly the letter R represents in organic chemical structures. Does the R always represent an alkyl group or can it represent groups with heteroatoms? For example
http://upload.wikimedia.org/wikipedia/commons/thumb/3/3a/Aldehyde2.png/60px-Aldehyde2.png
http://upload.wikimedia.org/wikipedia/commons/thumb/4/48/Ketone-general.png/60px-Ketone-general.png
there's the structure of an aldehyde and a ketone. Can I safely assume that the R's attached of the ketone will be Carbon atoms and will be attached to other C or H atoms. In other words will a ketone always have alkyl groups attached to its O=C or can a ketone have any elements in it?

The C of the O=C must be bound to others two C atoms, otherwise is not a ketone anylonger: if one is C and the other is H, it's an aldheide (if both are H it's Formaldehyde), if it's OH, is a carboxilic acid, etc.
 

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