What is the difference between gibbs free energy and activation energy

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SUMMARY

The discussion clarifies the distinction between Gibbs free energy (ΔG) and activation energy in chemical reactions. Gibbs free energy is defined as a thermodynamic quantity that indicates the spontaneity of a reaction, represented by the equation ΔG = ΔH - TΔS. In contrast, activation energy is the energy barrier that must be overcome for a reaction to proceed, denoted by the energy difference between the transition state and the reactants' enthalpy. The relationship between Gibbs free energy and enthalpy is illustrated through the equation ΔG = ΔH - TΔS, emphasizing the role of temperature and entropy in determining reaction feasibility.

PREREQUISITES
  • Understanding of thermodynamic concepts, specifically Gibbs free energy and activation energy
  • Familiarity with enthalpy diagrams and their components
  • Knowledge of the relationship between entropy and spontaneity in chemical reactions
  • Basic grasp of chemical kinetics and reaction mechanisms
NEXT STEPS
  • Study the implications of Gibbs free energy in chemical thermodynamics
  • Learn how to construct and interpret enthalpy diagrams for various reactions
  • Explore the role of temperature in affecting Gibbs free energy and reaction spontaneity
  • Investigate the concept of transition states and their significance in activation energy
USEFUL FOR

Chemistry students, chemical engineers, and researchers interested in thermodynamics and reaction kinetics will benefit from this discussion.

abi.ayan
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what is actually meant by gibbs free energy and what is the difference between gibbs free energy and activation energy?In an enthalpy diagram how can it be denoted(just like for activation energy is denoted by the energy difference between transition state and reactants' enthalpy)?I just search through but couldn't get a clear idea about gibbs energy.can anyone explain with an simple example?
 
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They have no similarities to begin with. As you have said, activation energy denotes the energy difference between transition state and reactants' enthalpy. But, Gibbs free energy is a term/ quantity whose dimensions happen to be that of energy.


ΔG = -TΔSuniverse = ΔH - TΔSsystem

And, as ΔSuniverse>0 for a spontaneous process, apparently ΔG<0.

So, it is just a quantity with the help of which we can say if a reaction proceeds forward or not.

The only way with which ΔG can be represented in an enthalpy diagram is through the relation

ΔG = ΔH - TΔS; where you can vary temperature and entropy.

Hope this explains it.
Best of luck!
Adithyan.
 
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