What is the hybridization of the nitrogen atom in aniline?

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The hybridization of the nitrogen atom in aniline is best described as sp2. This is due to the nitrogen's involvement in the aromatic system of the benzene ring, which requires planarity for aromaticity. While some may argue for sp3 hybridization, the sp2 designation is more accurate as it reflects the nitrogen's role in resonance with the aromatic system. All atoms in aniline must be planar to satisfy the planarity rule for aromatic compounds.

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Hey friends, can someone tell me the hybridization of the nitrogen atom in aniline? I think it should be sp3 but I am not sure. Also, should all atoms in the molecule be planar to satisfy the planarity rule for aromaticity?
 
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Ashu2912 said:
Hey friends, can someone tell me the hybridization of the nitrogen atom in aniline? I think it should be sp3 but I am not sure. Also, should all atoms in the molecule be planar to satisfy the planarity rule for aromaticity?

Atoms do not "have" a unique hybridization. It's only a description. A description in terms of sp2 or sp3 will be equally good in the case of aniline.
 

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