What is the molar heat capacity of an ideal gas at constant pressure and volume?

Click For Summary
SUMMARY

The molar heat capacity at constant pressure (Cp,m) for the ideal gas is calculated to be 29.25 J/K mole, based on the supplied heat of 117 J to 2.00 moles resulting in a temperature increase of 2.00 K. The relationship between Cp,m and Cv,m is established as Cv,m = Cp,m - R, leading to a calculated Cv,m of 12.621 J/K mole. The gas is identified as monatomic since its Cv,m aligns with the theoretical value of 3/2R for monatomic gases.

PREREQUISITES
  • Understanding of the ideal gas law (PV = nRT)
  • Knowledge of heat transfer and specific heat capacities
  • Familiarity with the concepts of molar heat capacities (Cp,m and Cv,m)
  • Basic principles of thermodynamics related to isobaric and isochoric processes
NEXT STEPS
  • Study the derivation of molar heat capacities for different types of gases
  • Learn about the equipartition theorem and its application to monatomic and diatomic gases
  • Explore the relationship between heat capacities and molecular degrees of freedom
  • Investigate real gas behavior and deviations from ideal gas laws
USEFUL FOR

Students studying thermodynamics, physicists, and chemists interested in the properties of gases and heat transfer principles.

Banyans
Messages
3
Reaction score
0

Homework Statement



117 J of energy is supplied as heat to 2.00 moles of an ideal gas at constant
pressure, the temperature rises by 2.00 K. Calculate the molar heat capacity at
constant pressure C_p,m and the molar heat capacity at constant volume C_v,m
for the gas. Is the gas monatomic or diatomic?

Homework Equations


PV = nRT
ΔQ = n Cp ΔT

The Attempt at a Solution


ΔQ = 117 J
n = 2 moles
ΔT = 2 K

ΔQ = n Cp ΔT = n αR ΔT
Cp = ΔQ/ (nΔT) = 29.25 J/K mole
Cp/R = 3.52

For ideal gases equation of state is
PV = nRT,
and work performed by the gas in isobaric process is
dA = PdV = nRdT,
which means Cv = Cp - R = 2.52 R.

But I have no idea how to relate this information to work out if its diatomic or monatomic.
 
Physics news on Phys.org
What is Cp for an ideal monoatomic gas?
 
Hello Banyans, :welcome:

Hard to give a hint here without spoiling the exercise. Don't the values of ##{7\over 2}## and ##{5\over 2}## ring a bell ? What would they be for an ideal monatomic gas ?
 
mfb said:
What is Cp for an ideal monoatomic gas?
5/2R?
 
So would I proceed in the following way?

Cp=29.25

Cp=Cv+nR
29.25=Cv+2(8.31451)

so

Cv=12.621

So there fore its a monoatomic gas? since Cv=3/2R?
 
Banyans said:
5/2R?
That is Cp for a monoatomic gas, right. Does that match the result you got for the unknown gas?
Banyans said:
Cp=Cv+nR
That formula is not right. Use specific heat capacities or use total heat capacities, but do so in a consistent way.
 

Similar threads

  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 11 ·
Replies
11
Views
2K
  • · Replies 8 ·
Replies
8
Views
3K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 61 ·
3
Replies
61
Views
6K
Replies
1
Views
35K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 9 ·
Replies
9
Views
2K
  • · Replies 10 ·
Replies
10
Views
4K