I think the OP is asking about vector-valued forms, of the form
[tex]\omega = \omega^a{}_\mu \vec e_a \; dx^\mu[/tex]
One can think of this object either as a 1-form whose components are vectors, or as a vector whose components are 1-forms. I think in this case, the latter description is easier. Then, a vector of 1-forms is exact if and only if each of its component 1-forms is exact.
In particular, for any vector field [itex]\vec F[/itex], the vector-valued 1-form [itex]d \vec F[/itex] is exact by definition.