What is the Relationship Between Seebeck Coefficient and Temperature Gradient?

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    Coefficient Confusion
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SUMMARY

The Seebeck coefficient quantifies the voltage generated per unit temperature difference across a conductor, as defined by Goldsmid. It is essential to have a temperature gradient across a junction for the Seebeck coefficient to be applicable. While the Seebeck coefficient is a material property, measuring the Seebeck effect requires two dissimilar materials, where the effective measurement is the difference in their Seebeck coefficients multiplied by the temperature difference. This relationship highlights the importance of both material properties and temperature gradients in thermoelectric applications.

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mcodesmart
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The Seebeck coefficient is the differential drop in voltage per unit temperature across a conductor. Goldsmid says that there must be a temp. gradient across a junction for a seebeck coefficeint to be defined. This makes sense if the difference in the fermi level energy between two dissimilar contacts that causes a change in energy of the electron as it jumps from one metal to another.

But I usually hear that the Seebeck coefficient is the property of the metal itself.

Any comments to clear this up would be received.
 
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