What is the relationship between wavelength and probability for matter waves?

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SUMMARY

The discussion centers on the relationship between wavelength and probability for matter waves, specifically addressing the de Broglie equation (λ = h/p) for electrons and photons. It is established that for electrons, the wavelength derived from the de Broglie equation represents the wavelength of the probability function as per Schrödinger's wave equation, rather than a physical wavelength. In contrast, for photons, this wavelength corresponds to their actual physical wavelength. The uncertainty principle is also highlighted, indicating that if a particle's momentum were known to be zero, its wavelength would be infinite, which is not physically meaningful.

PREREQUISITES
  • Understanding of the de Broglie equation (λ = h/p)
  • Familiarity with Schrödinger's wave equation
  • Knowledge of the uncertainty principle in quantum mechanics
  • Basic concepts of wave-particle duality
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  • Explore the implications of the uncertainty principle on quantum measurements
  • Investigate the differences between wave functions for particles and photons
  • Learn about electron diffraction experiments, such as Bragg reflection
  • Examine the practical applications of de Broglie's hypothesis in quantum mechanics
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Students and professionals in physics, particularly those focusing on quantum mechanics, wave-particle duality, and the foundational principles of wave functions and probability in quantum systems.

bhthiang
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I was told that for an electron, the wave length lamda calculated from De Broglie's equation ( = h/p ) refers to the wave length of its probability function (as solution to Schroedinger's wave equation ), and is not its physical wave length as exhibited in the electron's double slit diffraction nor diffraction through crystals.

At the same time, for photons we take lamda= h/p as the actual/physical wave length of the light.

Can someone shed some light on this apparent inconsistency?
 
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Originally posted by bhthiang
I was told that for an electron, the wave length lamda calculated from De Broglie's equation ( = h/p ) refers to the wave length of its probability function (as solution to Schroedinger's wave equation ), and is not its physical wave length as exhibited in the electron's double slit diffraction nor diffraction through crystals.

At the same time, for photons we take lamda= h/p as the actual/physical wave length of the light.

Can someone shed some light on this apparent inconsistency?

I don't see any inconsistency. If you perform an electron diffraction experiment (for example, Bragg reflection in a crystal lattice) diffraction will occur for specific values of d (lattice spacing), theta (angle of incidence) and lambda. If you can get values for d and theta, and calculate the wavelength, it should correspond (within experimental error) to the theoretical value given by the de Broglie relation.
 
Speaking of the de Broglie equation I noticed that if it were possible to know that a particles momentum was zero then it's wavelength would be infinitely long? So does the uncertainity principle prevent you from making a measurement of zero for the momentum of a particle since then you would be able to know it's position?
 
Originally posted by bdkeenan00
Speaking of the de Broglie equation I noticed that if it were possible to know that a particles momentum was zero then it's wavelength would be infinitely long? So does the uncertainity principle prevent you from making a measurement of zero for the momentum of a particle since then you would be able to know it's position?

The HUP says that dx*dp = h. That is, the product of the uncertainty in x (position) and p (momentum) is equal to a constant h (Planck's constant). So, the smaller one of these gets, the larger the other one does to keep this relation. Or, the more precisely we know one value, the less precisely we know the other.

So, if we could measure the momentum of a particle to be exactly zero, then technically it would have infinite wavelength, which is of course not physically meaningful. The HUP prevents this from happening. If we measured exactly 0 for p, then dp would also be 0, meaning dx would have to be infinite -- clearly, we could not tell anything useful about its position with an infinite uncertainty (not to mention the above equality would be violated).
 
The Uncertainty Principle works with ... uncertainties. Nothing can stop you from measuring p=0. But are you ABSOLUTELY SURE you measured 0? Or you measured 0 &plusmn something? That something is your uncertainty. If you're absolutely sure (which you can't be because you measure with something that makes some aproximations) then you get an infinite uncertainty for the position. This doesn't stop you though to measure the position. You'll get a value, but you'll have to mean value &plusmnn infinity.
 
thank you everyone for your reply!I see what you both mean but I'm pretty sure that my lamp is at rest relative to me so it has zero momentum relative to me. So does that mean that the de broglie equation is not always true for macroscopic objects? Is there an uncertainity I'm not aware of?
 
The de Broglie relation can be applied to macroscopic objects, but it is generally not meaningful. Take your lamp for example. Let's say the mass was 1 kg, and we threw it through the air at some velocity, say 10 m/s. If you calculcate it's wavelength, you will get something on the order of 10^-35 m, which is far too small to measure experimentally. For comparison, the diameter of a typical atom is on the order of 10^-10 m, or 25 orders of magnitude greater than your lamp's wavelength. Basically, this means that we cannot observe the "wave" nature of your lamp, and we would treat it as a pure "particle".
 
To Futz:

Thanks for your reply.

So what you are saying is that the "physical" wavelength is also the wavelength of the wave function, whose modulus calculated at a location represents the probability of finding the electron at that position?

Can we apply this to photons and say that their wavelengths are the same as the wavelengths of their wave function?
 

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