Whats is the difference between crystalline and non-crystalline ceramics?

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Discussion Overview

The discussion focuses on the differences between crystalline and non-crystalline ceramics, specifically addressing the characteristics of amorphous ceramics such as glass compared to crystalline solids.

Discussion Character

  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • Some participants clarify that non-crystalline refers to amorphous ceramics, such as glass.
  • One participant explains that amorphous solids lack long-range atomic order but have short-range order, contrasting this with crystalline solids that exhibit long-range order.
  • A participant provides a definition of crystalline solids, citing a source that describes them as having an orderly repeating pattern in three dimensions.
  • Examples are given, such as the difference between crystalline quartz and amorphous silica glass, with a note on how cooling rates affect the formation of these materials.
  • One participant mentions that the presence of air bubbles can be an optical method to distinguish between crystalline and amorphous forms, with crystalline forms typically lacking bubbles.
  • A fun fact is shared about opal being an amorphous form of SiO2, suggesting it can be considered a type of glass.

Areas of Agreement / Disagreement

Participants generally agree on the definitions and characteristics of crystalline versus non-crystalline ceramics, but the discussion remains open to further exploration of these concepts.

Contextual Notes

The discussion includes references to external sources for definitions, and there may be assumptions about the audience's familiarity with terms like "long-range order" and "short-range order." The explanation of cooling rates and their effects on material formation is presented as a simplified view.

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whats is the difference between crystalline and non-crystalline ceramics?
 
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By non-crystalline, is one referring to amorphous ceramics such as glass?
 
Astronuc said:
By non-crystalline, is one referring to amorphous ceramics such as glass?

yeah
 
Non crystalline solids or in other words "Amorphous" solids do not have any long-range atomic order... Amorphous solids do have short range order but lack long range structural periodicity.

http://en.wikipedia.org/wiki/Amorphous_solid

But crystalline solids have very long-range orders.

Quote from WikiPedia:
"A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions"

http://en.wikipedia.org/wiki/Crystals

A simple example is Quartz (Amethyst, Citrine etc = SiO2 crystal) vs Silica-Glass (SiO2 Amorphous)

A very rapid cooling of molten SiO2 may result in formation of the amorphous glass because enough time has not been made available for the molecules to get in order. (this is very simplified view :p )
While a slow cooling of the melt is more likely to produce the crystalline SiO2.

To distinguish these two types of SiO2; The best optical way, if the solids are transparent is looking for Air Bubbles in the solids. Crystalline form usually lacks any Bubble BUT the amorphous type will certainly have MASSIVE and Uncountable number of tiny or large bubbles visible under 10X magnification!

By the way, One fun fact; Did you know Opal (the gemstone) is an amorphous SiO2 ! So strictly speaking its a kinda glass.


Best Wishes :)
 
Last edited:

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