juanrga
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twofish-quant said:OK. Suppose the satellite is a hydrogen atom, and you are trying to calculate the properties of a large number of "satellites". At this point, the kinetic energy of the satellites *becomes* the internal energy of gas of satellites.
No. If I assume that atoms can be treated classically as point-like particles then the thermodynamic internal energy of the gas of atoms is not the kinetic energy of the gas. The thermodynamic internal energy of a gas is defined as the total energy minus the average macroscopic kinetic energy.
twofish-quant said:There are several other ways of calculating this. You can use the virial theorem or the equipartition theorem. See
http://en.wikipedia.org/wiki/Equipartition_theorem
http://en.wikipedia.org/wiki/Virial_theorem
From the wikipedia link:
In mechanics, the virial theorem provides a general equation relating the average over time of the total kinetic energy, \left\langle T \right\rangle, of a stable system consisting of N particles, bound by potential forces, with that of the total potential energy, \left\langle V_\text{TOT} \right\rangle, where angle brackets represent the average over time of the enclosed quantity.
But thermodynamics --which is not mechanics-- deals with internal energy, which is neither total kinetic energy nor total potential energy.
twofish-quant said:Yes it does. You change those satellites into atoms and then have several gazillion of them. At which point you have a gas.
A gas is not defined as a N-collection of particles with N large. If you were right then virtually every macroscopic piece of matter would be a gas and is not
twofish-quant said:Except that you don't. You have the internal energy of the gas which consists of the kinetic energy of the gas molecules (H), and then the potential energy of the gravitational field (U). The relationship between the two are defined by the equipartition theorem and the virial theorem. Because the sign of the potential energy is negative, what happens is that as you remove total energy from the system, the kinetic/internal energy of the gas increases. (It's annoying here, because we are running out of letters.)
Using standard notation (i.e. letters)
E = U + K + V
In mechanics kinetic energy is often denoted by T, but in thermodynamics T is temperature and K is standard symbol for kinetic energy.
If you insist on confound internal energy U with kinetic energy K or with potential energy V, then you can obtain virtually any result. The sum (K+V) is usually named mechanical energy. This mechanical energy is what mechanics is interested in. This mechanical energy verifies virial theorem. Read again the vikipedia link that you give. Pay attention to the first two words.
Thermodynamics is usually interested in U: internal energy. Indeed, thermodynamic textbooks contains a chapter introducing the concept of internal energy and its main properties.
twofish-quant said:You are missing a term. The problem is that the field is not an external field but the result of self-interactions. What that means is that you have an extra \partial (\tau_k) / \partial t term which includes how the gravitational potential changes in response to external interactions.
This is off the top of my head so don't shoot me if there is a problem (and I'm getting confused with all of the letters meaning different things), but if you add energy into a gravitationally bound system then the \partial (\tau_k) / \partial t is going to be strongly positive which means that once you add that term then c_V is going to turn negative.
I'm not surprised that someone that isn't familiar with stars would make that mistake, since in laboratory experiments interacting with the system doesn't change the potential, but in self-gravitating systems, it does.
First, \tau_k is the coupling constant, not the gravitational potential.
Second, as is well-known, the thermodynamic expression
\frac{\partial u}{\partial t} = c_V \frac{\partial T}{\partial t} + (u_k + \tau_k \psi) \frac{\partial n_k}{\partial t}
can be also rewritten as
\frac{\partial \tilde{u}}{\partial t} = c_V \frac{\partial T}{\partial t} + (u_k + \tau_k \psi) \frac{\partial n_k}{\partial t} + \tau_k \frac{\partial \psi}{\partial t}
using \tilde{u} = u + \tau_k \psi.
Of course the value of the heat capacity c_V is the same, because in the first case one takes partial derivative of internal energy u at constant composition and, in the second case, one takes the partial derivative of \tilde{u} but maintaining also constant \psi evidently.
twofish-quant said:One other wrinkle is that hydrodynamics beats thermodynamics. A star takes a few minutes to reach hydrodynamic equilibrium, but several thousand years to reach thermodynamic equilibrium. Because of these time scale differences, the hydrodynamics drives the thermodynamics. What that means is that if you add energy to the system, the hydro will cause the change to happen immediately that create temperature gradients that cause the system to go out of general thermodynamic equilibrium.
So you start with an isothermal gas, and add energy to it. Rather than staying in thermodynamic equilibrium, the energy will get distributed hydrodynamically, which will throw the system out of thermo equilibrium.
It seems you are confused about what thermodynamics really is and does. It is well-known that thermodynamics extends the balance laws of hydrodynamics in many ways. For instance, the balance law for internal energy contains the heat flux q and the term \pi:\nabla v, where \pi, is the dissipative pressure tensor. q and \pi are non-hydrodynamical quantity, unless you want to reinvent hydrodynamics also
twofish-quant said:No confusion. You have total energy which consists of internal energy + potential energy. Internal energy consists of kinetic energy of the gas molecules + internal degrees of freedom. Equipartition and virial theorems give you very simple relationships between these quantities. So once you have figured out the total energy, the virial theorem gives you the relationship between that and the internal energy and the potential energies.
The total energy E of a gas is E = K + V + U, with K the total kinetic energy, V the total potential energy and U the internal energy. The virial theorem of mechanics (read the wikipedia link that you give) applies to K and V (unsurprisingly K+V is named the mechanical energy). The virial theorem does not apply to U.
If you insist on confounding thermodynamic quantities with mechanical quantities then you can obtain any bizarre result that you want even dS<0.
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