The probability for each decay mode is expressed in terms of the branching ratio [tex]\Gamma_i/\Gamma[/tex], where [tex]\Gamma_i[/tex] is the partial decay rate for the specific process and
[tex]\Gamma = \sum_i \Gamma_i[/tex]
is the total decay rate. The mean lifetime is [tex]\tau = 1/\Gamma[/tex].
It is possible to define a partial lifetime [tex]\tau_i = 1/\Gamma_i[/tex] for each decay mode. This doesn't really have the same significance as a mean lifetime, because all of the decay modes compete. So whereas we can define a total half-life
[tex]\tau_{1/2} = \tau \ln 2[/tex]
as the time it takes for half of the pions in a sample to decay, a quantity like
[tex]\tau_{e^+\nu_e} \ln 2[/tex]
doesn't really correspond to the time it takes for half of a sample of [tex]\pi^+[/tex] to decay to positrons, since over that period of time, most of the sample will have instead decayed to muons.