Which Electronegativity Pairing is More Electronegative?

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SUMMARY

The discussion centers on the electronegativity of bromine (Br2), potassium bromide (KBr), and hydrogen bromide (HBr). It is established that Br2 has the lowest electronegativity due to equal sharing of electrons between the two bromine atoms. KBr is more electronegative than HBr because potassium (K) and bromine (Br) have a greater difference in electronegativity compared to hydrogen (H) and bromine. Understanding the periodic trends in electronegativity is crucial for ranking these compounds accurately.

PREREQUISITES
  • Understanding of electronegativity as a property of elements
  • Familiarity with the periodic table and its trends
  • Basic knowledge of chemical bonding concepts
  • Ability to interpret electronegativity differences between elements
NEXT STEPS
  • Research the electronegativity values of elements using the Pauling scale
  • Learn about periodic table trends in electronegativity
  • Study the concept of bond polarity and its relation to electronegativity
  • Explore how to calculate electronegativity differences for various compounds
USEFUL FOR

Chemistry students, educators, and anyone interested in understanding chemical bonding and electronegativity trends in the periodic table.

Lori

Homework Statement



Br2, KBr, and HBr

Homework Equations


none

The Attempt at a Solution


I understand that Br2 would be least electronegative because they both equally share the electrons, but i don't understand why KBr is more electronegative than HBr. This question was on my quiz, and i wasn't given a table of the electronegatives, so i had to think about it.

Can someone explain how i could find out if one is more electronegative than the other based on the periodic table? Is there like a periodic table trend for electronegativity for bond pairs?

Thanks[/B]
 
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Looks to me like you are confused about something. Electronegativity is a property of an element, not of a bond or a substance. Perhaps what you mean is just the difference between electronegativities of the elements involved? If so, it just about subtracting them, no need to look for any explanation.
 
Borek said:
Looks to me like you are confused about something. Electronegativity is a property of an element, not of a bond or a substance. Perhaps what you mean is just the difference between electronegativities of the elements involved? If so, it just about subtracting them, no need to look for any explanation.
I think that's the case. But, it was on my pop quiz for chem and we were told to rank the pairs based on electronegativity. The problem was I didn't* get the electronegative numbers for each element.

Is there a rule to like estimate the differences? I know that Br2 is least electronegative since the difference is 0
 
Does anyone know how i can figure out the ranking without knowing the electronegativity values? Perhaps, there is something conceptually i don't know about? I'm confused on how i know the Hbr is less electronegative than Kbr
 
Lori said:
Does anyone know how i can figure out the ranking without knowing the electronegativity values? Perhaps, there is something conceptually i don't know about? I'm confused on how i know the Hbr is less electronegative than Kbr

Hey Lori! :oldsmile:

Consider that the periodic system looks like the following with electronegativity.
And note that H and K are both in group 1, and K and Br are both in period 4.

H
##\uparrow## (increasing electronegativity)
K ##\rightarrow## (increasing electronegativity) Br

From this diagram we can conclude that the difference between Br and K must be greater than the difference between Br and H.
 
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Lori said:
The problem was I didn't* get the electronegative numbers for each element.

Its chemistry, you should have learned them by heart :-)
 

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