Which ∆H Should Be Used in Chemical Equations and Potential Energy Diagrams?

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Discussion Overview

The discussion revolves around the appropriate enthalpy change (∆H) to use in chemical equations and potential energy diagrams, based on experimental data from calorimetry labs. Participants explore different ways to express ∆H, including per gram and per mole of substance.

Discussion Character

  • Technical explanation, Conceptual clarification, Homework-related

Main Points Raised

  • One participant calculated ∆H for the entire system, per gram, and per mole, and is seeking guidance on which value to use in chemical equations and potential energy diagrams.
  • Another participant suggests using ∆H on a per mole basis for the equations.
  • A further reply indicates that using moles is likely correct and recommends writing out a proper unit formula to determine the appropriate value based on what cancels out in the calculations.

Areas of Agreement / Disagreement

There is a general inclination towards using ∆H per mole, but no consensus is firmly established, as some participants provide varying levels of support for this approach.

Contextual Notes

Participants have not fully resolved the implications of using different units (grams vs. moles) in their calculations, and the discussion does not clarify the specific conditions under which each might be appropriate.

rowkem
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So,

I did 5 labs where I burned certain things and found the temp. diff. in the calorimeter. That said, I calculated the ∆H for the entire system, the ∆H per gram of system substance, and the ∆H per mol of system substance.

Im wondering which ∆H I should be putting into my chemical equation for the reaction, as well the ∆H I should be putting into my potential energy diagram? I have a feeling its the ∆H per mole but, I'd like a second opinion. Thanks,
 
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You should do it on a per mole basis.
 
Most likely you want to use the mols of the substance in your equations. Write out a proper unit formula and you can see for sure whether you need the mols or grams based on what cancels and what you end up with.
 

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