Why are more x-rays made from metal than glass

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Discussion Overview

The discussion centers on the reasons why x-rays are more effectively produced from metal anodes compared to glass, particularly in the context of x-ray generation mechanisms such as electron interactions and bremsstrahlung. Participants explore both theoretical and historical aspects of x-ray production.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Historical

Main Points Raised

  • Some participants explain that x-rays are produced when high-energy electrons knock out core electrons from atoms, leading to the emission of x-ray photons or Auger electrons, with the quantum yield of x-rays increasing with atomic number.
  • It is noted that lighter elements, such as those found in glass (primarily silicon and oxygen), yield more Auger electrons, while heavier metals like iron or tungsten produce more x-rays, with a crossover point around zinc (Z = 30).
  • Another participant introduces the bremsstrahlung process, stating that metals allow for higher potential settings than insulators like glass, enabling more efficient electron collection and collision with the anode.
  • The density of metals is mentioned as a factor that contributes to their efficiency in stopping penetrating electrons, which in turn affects the energy of the bremsstrahlung radiation produced.
  • Follow-up questions are raised regarding the relationship between bremsstrahlung efficiency and the density or charge of the nucleus, as well as the reasons behind the differing behaviors of lighter and heavier elements in producing Auger electrons versus x-ray fluorescence.
  • One participant expresses confusion about the dependence of the probability of producing x-rays versus Auger electrons on atomic number.

Areas of Agreement / Disagreement

Participants generally agree on the mechanisms of x-ray production and the role of atomic number, but questions remain regarding the specifics of these processes and the reasons behind the observed behaviors, indicating unresolved aspects of the discussion.

Contextual Notes

Limitations include the lack of consensus on the underlying reasons for the dependence of x-ray versus Auger electron production on atomic number and the relationship between bremsstrahlung efficiency and atomic properties.

Cool4Kat
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i know that x-rays are produced when a beam of high energy electrons hits a metal anode but why does that work better than when that same beam hits glass (like in the Crookes tube)?

Thanks
 
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When an energetic electron hits an atom it can knock out a core electron. Then one of two things can happen:
(i) An electron from a higher shell can fall into the vacancy in the lower shell, accompanied by the emission of an X-ray photon.
(ii) An electron from a higher shell can fall into the vacancy in the lower shell, while another outer electron is expelled from the atom (Auger electron).
The quantum yield of X rays increases with atomic number; light elements give mostly Auger electrons and heavy elements mostly X rays. The crossover is somewhere around zinc (Z = 30). Thus glass, containing mainly Si and O, will give a lower yield of X rays than a heavier metal, such as iron or tungsten.

Thus much I know from my acquaintance with SEM. Why things are that way round, I don't know.
 
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mjc123 said:
When an energetic electron hits an atom it can knock out a core electron. Then one of two things can happen:
(i) An electron from a higher shell can fall into the vacancy in the lower shell, accompanied by the emission of an X-ray photon.
(ii) An electron from a higher shell can fall into the vacancy in the lower shell, while another outer electron is expelled from the atom (Auger electron).
The quantum yield of X rays increases with atomic number; light elements give mostly Auger electrons and heavy elements mostly X rays. The crossover is somewhere around zinc (Z = 30). Thus glass, containing mainly Si and O, will give a lower yield of X rays than a heavier metal, such as iron or tungsten.

Thus much I know from my acquaintance with SEM. Why things are that way round, I don't know.

But this is not the only way to generate x-rays. The other is via bremsstrahlung process where the electrons generate the EM radiation because they are being slowed down. This is where it is relevant to the OP's question, i.e. why is it more efficient to generate x-rays with a metal anode.

First of all, obviously, it is because one can efficiently set a higher potential for a metal than for an insulator like glass. So electrons can easily be collected and diverted to collide with the metal anode.

But secondly, metals tend to be more dense than glass (at least, regular glass) and are able to more efficiently stop the penetrating electrons. The quicker they stop, the higher the energy of the bremsstrahlung radiation, which is why we tend to get x-rays if the incoming electrons have sufficiently high energy. This x-ray generated via bremsstrahlung is a very common radiation in particle accelerators, especially when there are stray high energy electrons hitting the stainless steel beam pipe.

Zz.
 
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Thank you so much. I was actually interested because of the history of the x-ray and the x-ray machine. I have two follow up questions:

1. Does the bremsstahlung have to do with the density *or* the charge of the nucleus? Or, is that basically the same thing?

2. Do you know why lighter elements create mostly Auger electrons and the heavier elements create mostly x-ray fluorescence?

Thanks again
 
Thank you so much for replying. I really appreciate it.
 
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<Moderator's note: Merged from another thread.>

It seems pretty clear that when a core electron is ejected and another electron falls into that hole, it can either release that energy in a photon or in ejecting another electron. That makes plenty of sense to me. What I can't understand is why the percent chance of getting an x-ray vs. a Auger electron is dependent on the atomic number.

Any of you smart lovely people know the answer?

Danka,

Kathy
 

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