Why do some materials reflect and others absorb light?

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    Absorbtion Reflection
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Discussion Overview

The discussion revolves around the reasons why some materials reflect light while others absorb it, with a focus on the role of energy bands and dielectric constants. Participants explore the concepts of transparency, opacity, and reflection in materials, touching on both theoretical and practical aspects.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant suggests that the behavior of materials regarding light absorption and transmission can be explained by energy bands, where the ability of electrons to absorb photons determines whether a material is opaque or transparent.
  • Another participant questions the terminology used, clarifying that "energy bands" was meant instead of "energy belts," and expresses skepticism about the FAQ's ability to address the nuances of reflection.
  • A later reply discusses the complexity of reflection, noting that metallic surfaces, which contain free electrons, are primarily responsible for reflection in the visible range due to a phenomenon referred to as "plasmon" collective state.
  • One participant introduces the concept of the dielectric constant, stating that materials with an imaginary part in their dielectric constant are absorptive and also reflective, indicating a relationship between absorption and reflection in certain substances.
  • Another participant mentions that different mechanisms are involved in the reflection of light compared to ionized particle radiation, suggesting that the topic encompasses various interpretations and resources for further exploration.

Areas of Agreement / Disagreement

Participants express differing views on the explanations for reflection and absorption, with no consensus reached on a singular model or understanding of the phenomena discussed.

Contextual Notes

There are unresolved aspects regarding the definitions of terms like "energy bands" and the implications of dielectric constants on material properties. The discussion also reflects varying levels of understanding and interpretation of the mechanisms involved in light interaction with materials.

jostpuur
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If the question was that why are some materials opaque and why some are transparent, the answer would be found in the energy bands. If energy bands allow such transitions for electrons, that they can absorb photon, then they will absorb it, and the photon does not go through the material. If electrons instead cannot absorb a photon, then the photon will go through the material.

Was that right?

Well then the next question is that why are some materials reflective and some absorptive? Can it be explained with the energy bands?
 
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What are "energy belts"?

There is an elementary explanation for photon transport in materials in the FAQ thread inside the General Physics forum. Maybe you should start with that first and see if you have any further question.

Zz.
 
I meant "energy band".

If you translate "band" into Finnish and then back to English, it easily becomes a "belt". :redface:

I don't believe that the FAQ answers my question. It contains something about absorption, but not about reflection.
 
jostpuur said:
I meant "energy band".

If you translate "band" into Finnish and then back to English, it easily becomes a "belt". :redface:

I don't believe that the FAQ answers my question. It contains something about absorption, but not about reflection.

I did say it is a "start".

Reflection is a bit more complicated, because it depends on the material. Most mirrors that you see are metals, so this clearly provides a clue on the process of reflection in the visible range. The free electrons form what is often-called the "plasmon" collective state, which is a surface phenomenon that is responsible for most reflection of such metallic surface.

Zz.
 
A material is absorptive if its dielectric constant has an imaginary part.
If epsilon_r is not equal to 1, it is also reflective, at least to some extent.
This makes strongly absorbing substances also highly reflective as can be seen e.g. in crystalls of pure dyes.

The dielectric constant can be calculated in the band approximation. The classical
reference being S. Adler, Quantum Theory of the Dielectric Constant in Real Solids, Phys. Rev. 126:413-20 (1962)
 

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