Why Does Energy Behavior Differ in Particle in a Box Model Versus Bohr's Theory?

In summary, the conversation discusses the contradiction between the increase in energy as n increases in the particle in a box model, while Bohr's theory shows a decrease in energy with increasing n. The speaker notes that the negative sign in Bohr's equation accounts for this difference and explains that in both cases, the energy is actually increasing. They also question the application of Bohr's model to a particle in a box.
  • #1
Lizwi
40
0
Hi, Please help me I am lost. I particle in a box model , equation for energy show that the energy increases as n increases, but in Borh's theory n^2 is in the denominator showing that as n increase, the energy decrease, I see the condradiction here. Am I right?
 
Physics news on Phys.org
  • #2
Why should we apply Bohr's model to a particle in a box? Regardless, note the negative sign in Bohr's equation. As the principal quantum number "n" increases the energy because less negative. So in both cases its getting higher.
 
  • #3
The Bohr energy is increasing even with n2 in denominator, because there is a negative sign. The energy is getting closer to zero from below - thus it is increasing.
 
Back
Top