The method of images is effective in electrostatics for calculating electric fields near conducting surfaces by using imaginary charges to satisfy boundary conditions. It relies on the uniqueness theorem, which states that if a solution for electric potential meets the boundary conditions and charge density, it is the only solution. This method allows for the clever arrangement of charges outside the region of interest to fulfill these conditions, often utilizing symmetries. By applying this technique, one can simplify complex problems in electrostatics. Ultimately, the method of images provides a unique and efficient way to solve for electric potentials in specific configurations.