Why does the singular potential solution reduce to a single coefficient?

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Homework Help Overview

The discussion revolves around the solution to a singular potential problem in quantum mechanics, specifically how the wavefunction reduces to a single coefficient under certain conditions. The context involves the Schrödinger equation and the properties of wavefunctions at a singular potential.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • The original poster attempts to understand the transition from the general solution of the Schrödinger equation to a specific form for the wavefunction. They question how imposing conditions of continuity and square integrability leads to the reduction of coefficients.
  • Some participants question the implications of square integrability and how it relates to setting certain coefficients to zero.
  • Others suggest evaluating integrals of the wavefunctions to determine convergence and divergence based on non-zero coefficients.

Discussion Status

The discussion is ongoing, with participants exploring the implications of mathematical conditions on the wavefunction. Some guidance has been offered regarding the evaluation of integrals to assess convergence, but no consensus has been reached on the reasoning behind setting specific coefficients to zero.

Contextual Notes

Participants are navigating the constraints of the problem, particularly the conditions imposed on the wavefunction due to the nature of singular potentials and the requirements for physical solutions in quantum mechanics.

ehrenfest
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My book says that the solution to a singular potential at zero problem has the form
<br /> \begin{array}{ccc}<br /> \psi(x) &amp;=&amp; A exp(Kx) for x&lt; 0 \\<br /> &amp; =&amp; Aexp(-Kx) for x &gt; 0 \end{array}<br />

How do you get that from the general solution of the Schrödinger equation
\hbar^2/2m d^2 \psi(x)/dx^2 = E \psi(x) = -|E|\psi(x)
which is
<br /> \begin{eqnarray*}<br /> psi(x) &amp;=&amp; A exp(Kx) + B exp(-Kx) for x&lt; 0 \\<br /> &amp; &amp;= Cexp(-Kx) + Dexp(Kx)for x &gt; 0<br /> \end(eqnarray*}<br />

by "imposing the condition that the wavefunction be square integrable and continuous at x = 0".

Obviously the second condition gives you A + B = C + D but I do not see how that helps reduce to a single coefficient.

And why are my equation arrays not working? :(
 
Last edited:
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the condition that it be square integrable means the we must set
B=D=0.
 
How does square integability imply that?
 
As a quick test, you want to evaluate each of those (modulus squared) integrals over their respective domains. Ask yourself which ones will converge and which will diverge (for non-zero coefficients)?
 
Last edited:
I see. Thanks.
 

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