Planar wave solution to zero potential Schrödinger equation

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Homework Help Overview

This discussion revolves around the planar wave solution to the zero potential Schrödinger equation, focusing on the mathematical representation of free particles in quantum mechanics.

Discussion Character

  • Mixed

Approaches and Questions Raised

  • Participants explore the implications of the wave function form ##\psi(x, t) = e^{i(kx - \omega t)}## and its derivatives. There are discussions about simplifying terms, the nature of the wave function, and the relationship between wavenumber and frequency. Some participants question the treatment of complex coefficients and the necessity of including both positive and negative exponentials in the wave function.

Discussion Status

The conversation is active, with various interpretations and approaches being discussed. Some participants have provided guidance on the mathematical treatment of the wave function, while others are exploring the implications of their findings. There is no explicit consensus yet, as different perspectives on the wave function's form and its components are being examined.

Contextual Notes

Participants are navigating the complexities of quantum mechanics, particularly in relation to the Schrödinger equation and the properties of wave functions. There are references to homework constraints and specific exercise requirements that influence the discussion.

Schwarzschild90
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Homework Statement


Schrödinger.PNG


Homework Equations


\begin{align}
\begin{split}
\psi(x, t) = e^{(ikx- i \omega t)}
\\
V(x) = 0
\end{split}
\end{align}

The Attempt at a Solution


For a free particle, the Schrödinger equation can be put in the form of ##\psi(x, t) = e^{(ikx- i \omega t)}##. With constant potentials for all x, ##\forall x : V = 0##, or put equally succinctly: ##V(x) = 0## (the function of which is time independent for all x in the domain)

\begin{align}
\begin{split}
i \hbar \frac{\partial \psi}{\partial t} = -\frac{\hbar^2}{2m} \frac{\partial^2 \psi}{\partial x^2} + V \psi
\end{split}
\end{align}

Make the substitution ##\psi(x, t) = e^{i(kx-\omega t)}##

\begin{align}
\begin{split}
i \hbar \frac{\partial}{\partial t} e^{i(kx- \omega t)} = \frac{\hbar^2}{2m} \frac{\partial^2}{\partial x^2} e^{i(kx- \omega t)}
\end{split}
\end{align}

Now, take the partial derivative with respect to time of the left hand side of the equation
\begin{align}
\begin{split}
i \hbar \frac{\partial}{\partial t} e^{i(kx- \omega t)} = -i^2 \hbar \omega e^{(ikx-\omega t)}
\end{split}
\end{align}

And the second order partial derivative with respect to x, of the right hand side of the equation

\begin{align}
\begin{split}
\frac{\hbar^2}{2m} \frac{\partial^2}{\partial x^2} e^{i(kx- \omega t)} = \frac{\hbar^2}{2m} (i^2k^2) e^{i(kx- \omega t)}
\end{split}
\end{align}

Moderator's note: post edited to fix the LaTeX. Use double # for inline equations, not $.
 
Last edited by a moderator:
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You should get rid of the ##i^2##. Otherwise, do you have a question?
 
And (2) ##\Rightarrow ## (4) + (5) = 0 gives you ?
 
@BvU: A homogenous partial differential equation

@DrClaude: I imagined that I would simplify a little later
 
Schwarzschild90 said:
@BvU: A homogenous partial differential equation

@DrClaude: I imagined that I would simplify a little later
$$ a = b\\c = d $$ gives a pde ## a=c ##, I agree :wink:.
 
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\begin{align}
\begin{split}
\frac{\hbar^2}{2m} (k^2) e^{i(kx- \omega t)} - \hbar \omega e^{(ikx-\omega t)} = 0
\\
\frac{\hbar}{2m} (k^2) e^{i(kx- \omega t)} = \omega e^{(ikx-\omega t)}
\end{split}
\end{align}

And cancelling an $\hbar$ right away
 
Bingo !

-- kudos for using the \split goody. Didn't know it. But it seems to confuse the \align thingy, perhaps because of the label rhs appearing twice ...​
 
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I see no reason not to cancel the following term

\begin{align}
\begin{split}
e^{i(kx- \omega t)}
\end{split}
\end{align}

but I've been wrong before :P
 
(6) has to be true for all t and all x, independently.
What is happening here is separation of the variables x and t.

Oh, and ##e^{iy} \ne 0 ## always, so why not ?
 
  • #10
So for a free particle (in a box) we have

\begin{align}
\begin{split}
k^2 = \frac{p^2}{\hbar^2}
\end{split}
\end{align}

But the wavenumber

\begin{align}
\begin{split}
k = \frac{\pi}{\lambda} \\
\left( \frac{\pi}{\lambda} \right)^2 = \frac{p^2}{\hbar^2} \to \left( \frac{\pi}{\lambda} \right) = \frac{p}{\hbar}
\end{split}
\end{align}
 
  • #11
Schwarzschild90 said:
So for a free particle (in a box) we have

\begin{align}
\begin{split}
k^2 = \frac{p^2}{\hbar^2}
\end{split}
\end{align}
Work with the equations ou already have. Don't introduce p here (which is an operator, since you are working in position space).
 
  • #12
And wasn't ##k = {2\pi\over \lambda } ## :wink: ?
(But I agree with Claudius)
 
  • #13
So I can use the following identity to separate variables

\begin{align}
\begin{split}
e^{iy} = \cos(y)+ i \sin(y)
\end{split}
\end{align}

And use the fact that

\begin{align}
\begin{split}
e^{i(kx- \omega t)} = e^{ikx} \times e^{- i \omega t}
\end{split}
\end{align}
 
  • #14
Since e^(iy) \neq 0 always, I could go ahead and cancel the term on both sides of the equation?
 
  • #15
All in favor !
 
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  • #16
Therefore k and omega need to be related in the following way

\begin{align}
\begin{split}
\frac{\hbar}{2m} k^2 = \omega(k)
\end{split}
\end{align}
 
  • #17
Isn't it nice ? And if we now take a sneak preview: with ##E = \hbar\omega\ \ \& \ \ \vec p = \hbar \vec k\ \ ## it looks like ##E = {p^2\over 2 m}## :smile: !
 
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  • #18
It's a ridiculously satisfying result :))

Should I let the angular velocity depend on k?
 
  • #19
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  • #20
Thanks :biggrin:
 

Attachments

  • Schrödinger b.PNG
    Schrödinger b.PNG
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Last edited:
  • #21
schroedinger-b-png.95531.png

Which function do you think the author of exercise b asks me to use?
 
  • #22
The one in (1).
You were already embarking on dissecting it in
Schwarzschild90 said:
So I can use the following identity to separate variables
\begin{align}
\begin{split}
e^{iy} = \cos(y)+ i \sin(y)
\end{split}
\end{align}And use the fact that\begin{align}
\begin{split}
e^{i(kx- \omega t)} = e^{ikx} \times e^{- i \omega t}
\end{split}
\end{align}
(and you remember that coefficients are complex numbers in QM)
 
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  • #23
That yields the following

\begin{align}
\begin{split}
e^{i(kx-\omega t)} = \cos{(i(kx-\omega t))} + i \sin{(i(kx-\omega t))} \\
Closest: \ cosh(k x-t \omega)-sinh(k x-t \omega)
\end{split}
\end{align}
 
  • #24
Re:
Schwarzschild90 said:
It's a ridiculously satisfying result :))
Should I let the angular velocity depend on k?
This ##\omega## is a totally different angular velocity.
I have become quite enthousiastic about these Feynman lectures (the link came from Simon Bridge) -- Richard Feynman talks about photons, but later on you understand that this is true for all and everything (except radioactivity and gravity :smile: ).

Re:
Schwarzschild90 said:
That yields the following

\begin{align}
\begin{split}
e^{i(kx-\omega t)} = \cos{(i(kx-\omega t))} + i \sin{(i(kx-\omega t))}
\end{split}
\end{align}
I seem to remember something like ##e^{ix} = \cos x + i\sin x## :smile:
 
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  • #25
The linear combination resulting is then

\begin{align}
\begin{split}
e^{i(kx-\omega t)} = \cos{(kx-\omega t)} + i \sin{(kx-\omega t)}
\end{split}
\end{align}

I'm very fond of watching Feynman's lectures as a way to cover more ground and to develop insight in physics
 
  • #26
Schwarzschild90 said:
The linear combination resulting is then
\begin{align}
\begin{split}
e^{i(kx-\omega t)} = \cos{(kx-\omega t)} + i \sin{(kx-\omega t)}
\end{split}
\end{align}
So, as answer to b), you write ##\ \Psi_s = \ \ ## ?? and ##\ \Psi_c = \ \ ## ??
 
  • #27
\begin{align}
\begin{split}
\Psi_c = \cos{(kx-\omega t)} \\
\Psi_s = i \sin{(kx-\omega t)}
\end{split}
\end{align}

I can't see how I get rid of the complex coefficient
 
  • #28
There is no reason to want to get rid of the complex coefficient (they are just fine, see #22). Wave functions have complex values.

However, you have another problem on your hand: From Euler you have an expression for ##\cos x## and it doesn't just contain ##e^{ix}## but also ##e^{-ix}##. In other words: you need to check that ##\ \Psi = e^{-i(kx-\omega t)}\ ## also satisfies the Schroedinger equation (1.1) and then determine ##C_1## and ##C_2## in ##\ \Psi_s = \ \ C_1 e^{i(kx-\omega t)} + C_2 e^{-i(kx-\omega t)}## .

Idem ##\Psi_c##

Note that (7) can't be the answer: they are part of the problem statement for (b) !
 
  • #29
\begin{align}
\begin{split}
-\omega = \frac{\hbar}{2m} k^2
\end{split}
\end{align}
 
  • #30
Are we running into trouble here ?
 

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