Why is My Lattice Energy Calculation for PbCl2 Different from the Book's?

In summary, lattice energy is the energy released when gaseous ions form a solid crystal lattice and is a measure of the strength of the ionic bonds in a compound. It is calculated using the Born-Haber cycle, which considers the formation of ions, dissociation of molecules, and combination of ions. The charges and sizes of ions, as well as the distance between them, affect the lattice energy of a compound. The lattice energy of PbCl2 can be determined experimentally or calculated using theoretical models such as the Born-Lande equation. Understanding the lattice energy of PbCl2 is important in determining the stability, properties, solubility, melting point, and reactivity of the compound.
  • #1
cuallito
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Homework Statement
Determine the lattice energy of PbCl2
Relevant Equations
Lattice energy= Heat of formation- Heat of atomization- Dissociation energy- (sum of Ionization energies)- (sum of Electron Affinities)
Here's my attempt at solving it using Hess's Law. I get -1770kJ when I add up all the numbers. The correct answer is supposed to be -2484 kJ.

lattice energy.png
 
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  • #2
I forgot to flip the sign for 2Cl(g)->Cl2(g), but I'm still not getting the right number:
1637001678311.png
 
  • #3
I agree with your calculation. Maybe the book's wrong - it happens.
 
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