Why is psi equal to psi' in vector expressions in QM?

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SUMMARY

The discussion clarifies the equality of the states |\psi\rangle and |\psi'\rangle in vector expressions within quantum mechanics (QM). Specifically, it addresses the expression involving the vector of Pauli spin matrices, \mathbf{m} = \{t_1, t_2, t_3\}, and the annihilation operator, a. The participants conclude that |\psi\rangle represents spatial physics while |\sigma\rangle denotes internal spin states, which exist in separate Hilbert spaces. This separation allows for the rearrangement of terms in the expression, confirming the equality of the states.

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Niles
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Hi guys

I am reading a book, where they use vector expressions a lot. In it they write

[tex] {\bf{M}} = \sum\limits_{\psi ,\psi ',\sigma ,\sigma '} {\left\langle {\psi '} \right|\left\langle {\sigma '} \right|{\bf{m}}\left| \sigma \right\rangle \left| \psi \right\rangle a_{\psi ',\sigma '}^\dag a{}_{\psi ,\sigma }} [/tex]

where m={t1, t2, t3} is the vector containing the three Pauli spin matrices t1, t2, t3 and a is the annihilation operator. They say this is equal to

[tex] {\bf{M}} = \frac{\hbar }{2}\sum\limits_{\psi ,\sigma ,\sigma '} {\left\langle {\sigma '} \right|\left( {t_1 ,t_2 ,t_3 } \right)\left| \sigma \right\rangle a_{\psi ,\sigma '}^\dag a{}_{\psi ,\sigma }} [/tex]

I cannot see why they equal psi = psi', since m is a vector, not a diagonal matrix. What are they doing here?
 
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Without having more details about what definitions the book is using, it appears that in the expression

[tex]{\left\langle {\psi'} \right|\left\langle {\sigma'} \right|{\mathbf{m}}\left| \sigma \right\rangle \left| \psi \right\rangle[/tex]

[tex]|\psi\rangle[/tex] is the state describing the spatial physics, while [tex]|\sigma\rangle[/tex] is an internal spin state. If this is true, these states lie in different Hilbert spaces. Furthermore, the operator [tex]\mathbf{m}[/tex] acts only on the spin states, not [tex]|\psi\rangle[/tex]. So we can rearrange

[tex]{\left\langle {\psi'} | \psi \right\rangle\left\langle {\sigma'} \right|{\mathbf{m}}\left| \sigma \right\rangle .[/tex]
 
Ah, of course... I should have known that. I will not forget it. Thanks, you have helped me a lot today. I really appreciate it.

Best wishes,
Niles.
 

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