Why ∆u=Cv ∆T for isochoric transformation of non-ideal gases?

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SUMMARY

The discussion centers on the equation ∆u = Cv ∆T, specifically in the context of isochoric transformations of non-ideal gases. It is established that for ideal gases, this equation holds true for all transformations, while for non-ideal gases, it is valid only during isochoric transformations. The definition of Cv is clarified as the limit of ∆u/∆T as ∆T approaches zero, emphasizing that internal energy for ideal gases depends solely on temperature. The relationship is derived from the first principle of thermodynamics, noting that in isochoric processes, the work done is zero, leading to the conclusion that Δu equals the heat added at constant volume (Qv).

PREREQUISITES
  • Understanding of the first principle of thermodynamics
  • Familiarity with the concepts of internal energy and heat capacity (Cv)
  • Knowledge of ideal versus non-ideal gas behavior
  • Basic principles of isochoric transformations
NEXT STEPS
  • Study the derivation of Cv for non-ideal gases
  • Explore the implications of the first principle of thermodynamics in various transformations
  • Investigate the differences between ideal and non-ideal gas equations of state
  • Learn about heat transfer mechanisms in isochoric processes
USEFUL FOR

This discussion is beneficial for students and professionals in thermodynamics, particularly those studying gas behavior, heat transfer, and energy transformations in physical systems.

maCrobo
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I simply report what I read:
"For an ideal gas, but for every kind of transformation ∆u=Cv ∆T, while for every kind of material in the thermodynamic system, but only for isochoric transformation ∆u=Cv ∆T."

Where does this second statement come from?
Everything is clear about ideal gases, but I don't figure out how to prove the second part of this statement.
 
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That is how Cv is defined.

Cv is the limit when ∆T goes to zero of ∆u/∆T. The first statement is simply a consequence of internal energy being dependent only of T for an ideal gas.
 
maCrobo said:
I simply report what I read:
"For an ideal gas, but for every kind of transformation ∆u=Cv ∆T, while for every kind of material in the thermodynamic system, but only for isochoric transformation ∆u=Cv ∆T."

Where does this second statement come from?
Everything is clear about ideal gases, but I don't figure out how to prove the second part of this statement.
It follows from the first principle of thermodynamics. In isochoric transformations the work (compression-expansion work) is zero so Δu=Qv.
 

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