The discussion centers on solving for the angle θ in X-ray diffraction using the equation nλ=2dsinθ. The user expresses confusion about how to approach the problem, particularly regarding the impact of thin films and the geometry of the crystal planes. It is noted that diffraction occurs only for planes at specific angles, and understanding the arrangement of the source, sample, and interference is crucial for determining the angle of the crystal planes. The conversation highlights the importance of making assumptions about wavelength (λ) and the order of diffraction (n) to compute the plane spacing (d). Ultimately, the user finds clarity and thanks the contributors for their assistance.