Yes, for all integers n, any two n-dimensional vector spaces are isomorphic. However, in the general case, you need something like a basis for each of the spaces to explicitly define the isomorphism. In this case, you just define, for each linear L:V→V, T_L(u^*,v)=u^*(L(v)) for all u^*\in V^* and all v\in V, and the map L\mapsto T_L is an isomorphism. No need to use any special bases, inner products, metrics or anything of that sort.
Another reason is that this identification between those two spaces works so well with the abstract index notation. In that notation, both L and TL above would be denoted by L^a{}_b. The map I denoted by L is v^b\mapsto L^a{}_b v^b, and the map I denoted by TL is (\omega_a,v^b)\mapsto L^a{}_b \omega_a v^b. (Here I'm denoting a typical member of V* by a Greek letter instead of by a Latin letter with an asterisk, because the asterisks would make the abstract index notation awkward).
I should probably tell you that I'm making another identification by isomorphism in the preceding paragraph. L^a{}_bv^b has a free index upstairs, so it should be interpreted as a (1,0) tensor, i.e. a member of V**. Specifically, it's the map u^*\mapsto T_L(u^*,v), which could be denoted by T_L(\cdot,v). But I'm using the isomorphism f:V\to V^{**} defined by f(v)(u^*)=u^*(v) for all v\in V and u^*\in V^*, to identify V with V**. Since f(L(v))(u^*)=u^*(L(v))=T_L(u^*,v)=T_L(\cdot,v)(u^*) for all u^*\in V^*, we have f(L(v))=T_L(\cdot,v). This means that the map T_L(\cdot,v) is the member of V** that the isomorphism f associates with L(v)\in V.
So when I said that L is denoted by L^a{}_b in the abstract index notation, that was strictly speaking not true, but I said it anyway, because you will see lots of statements like that in GR books. It's more accurate to say that L^a{}_b takes v^b to L^a{}_bv^b, which denotes T_L(\cdot,v)=f(L(v)), where f is the natural isomorphism from V to V**.
Yes, this is very confusing at first. It takes some time getting used to. I think the key to understanding these things is to understand the isomorphism I denoted by f, so if you don't understand it perfectly, you should start by making sure that you do.