Entropy - Help Water -> Ice

S = 10*4.18*ln (263/293) + 10*2.19*ln(263/253) = -0.1658 + -0.014 = -0.1798In summary, the conversion of 10 kg of H2o at 20 degrees C to ice at -10 degrees C by being put in contact with a reservoir at -10 degrees C, at constant pressure, results in a change in entropy of -0.1798 for the universe. This is due to the heat lost to the surroundings during the fusion process.
  • #1
ChronicQuantumAddict
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Entropy - Help! Water --> Ice

Here is my question:
10 kg of h2o at 20 degrees C is converted to Ice at -10 degrees C by being put in contact with a reservoir at -10 degrees C. The process takes place at constant pressure. The heat capacities at constant pressure of water (Cp_h2o) and Ice (Cp_ice) are
4180 and 2190 (J)/(kg)*(K)​
respectively. The heat of fusion of water, l_h2o, is
3.35x10^5 (J)/(kg).​
Calculate the change in entropy of the universe.

I know delta S_universe = delta S_system + delta S_surroundings, but i am a little stuck, any pointers? :yuck:
 
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  • #2
During the fusion process , the heat would be lost to the surroundings which would lead to increase in entropy. The reservoir is at a fixed temperature (-10) and would gain heat ...therefore entropy change for surroundings = Q/T.

For the system , the change in entropy would be due to heat lost to the surroundings As the transformation in from H2o to ice ... the net entropy change would be:

dS = Ca ln (T2/T1) + Cb ln(T2/T3)

BJ
 

1. What is entropy?

Entropy is a measure of the disorder or randomness of a system. It is a thermodynamic property that describes the amount of energy that is unavailable for work in a system.

2. How does entropy relate to the process of water turning into ice?

During the process of water turning into ice, the entropy of the system decreases. This is because the molecules in the liquid water are more randomly arranged compared to the more ordered crystal structure of ice.

3. Can entropy be reversed in the process of water turning into ice?

No, entropy cannot be reversed. The second law of thermodynamics states that the total entropy of a closed system can never decrease, only stay the same or increase.

4. Is entropy the only factor that determines whether water will turn into ice?

No, there are other factors that can affect whether water will turn into ice such as temperature and pressure. These factors can also influence the entropy of the system.

5. How can we calculate the change in entropy during the process of water turning into ice?

The change in entropy can be calculated using the equation ΔS = Q/T, where ΔS is the change in entropy, Q is the heat absorbed or released during the process, and T is the temperature at which the process occurs.

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