Thermodynamic - water/ice piston help

In summary, an inventor has proposed a heat engine using water/ice as the working substance to lift a piston supporting a mass m. The engine process consists of four steps: load, lift, unload, and reset. The inventor believes this device can perform an unlimited amount of work while absorbing only a finite amount of heat each cycle. To calculate the work done by the piston and the required mass to stop the engine, one would need to consider the compressibility of water and ice.
  • #1
aiyoshi
1
0
An inventor proposes to make a heat engine using water/ice as the working substance inside a cylindrical piston and taking advantage of the fact that water expands as it freezes and can therefore lift a piston supporting some mass m. The engine process consists of four steps as shown in the schematic below.

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(i) Load: The weight to be lifted is placed on top of a piston over a cylinder of water held at a temperature of 1oC. The piston sits at height hw.
(ii) Lift: The system is then placed in thermal contact with a low temperature reservoir at −1oC until the water freezes into ice, lifting the weight to a height hi.
(iii) Unload: The weight is then removed at height hi while the ice remains frozen.
(iv) Reset: The ice is melted by putting it back in contact with the high-temperature reservoir at 1oC, returning the piston hw. Another mass is added to the piston and the cycle is ready to be repeated.

The inventor is pleased with this device because it can seemingly perform an unlimited amount of work (by lifting an unlimited mass m) while absorbing only a finite amount of heat each cycle.

Question
Assuming that the piston has a cross-sectional area of 10 cm2 and contains 50 cm3 of liquid H2O (i.e. homework = 5 cm), calculate:
(i) The work done by the piston in raising a mass of 10 g.
(ii) The mass required to stop the engine working (i.e., reduce the freezing point of the water to −1oC).
 
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  • #2
Interesting idea. For your questions:
1. W=FD
2. You will have to look into the compressibility of water and ice.
 

1. What is a water/ice piston in thermodynamics?

A water/ice piston is a device used in thermodynamics to demonstrate the concept of phase change. It consists of a cylinder with a movable piston that separates two compartments, one filled with water and the other with ice. As heat is applied, the ice melts and turns into water, causing the piston to move.

2. How does a water/ice piston illustrate the first law of thermodynamics?

The first law of thermodynamics states that energy cannot be created or destroyed, only transferred or converted. In the case of a water/ice piston, the heat applied to melt the ice is converted into work as the piston moves, demonstrating the conservation of energy.

3. What is the significance of the water/ice piston in studying thermodynamics?

The water/ice piston is a simple and visual way to understand the concepts of heat transfer, phase change, and work in thermodynamics. It also helps to illustrate the first and second laws of thermodynamics and their applications in various systems.

4. How does the water/ice piston demonstrate the second law of thermodynamics?

The second law of thermodynamics states that in a closed system, the total entropy (measure of disorder) will always increase over time. In the case of the water/ice piston, as heat is applied and the ice melts, the system moves towards equilibrium as the water and ice mix, and the entropy of the system increases.

5. What other applications does the water/ice piston have in thermodynamics?

The water/ice piston can be used to study various thermodynamic processes, such as isothermal, adiabatic, and isobaric processes. It can also be used to demonstrate the Carnot cycle and the efficiency of heat engines. Additionally, it can be used to investigate the relationship between temperature, pressure, and volume in a closed system.

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