What Is the Cardinality of Bloch Waves in Quantum Mechanics?

In summary, the solutions of the Schrodinger equation in a periodic potential can be expressed as superpositions of Bloch waves, with either a continuous or discrete wave vector parameter. These superpositions are still periodic and there can be multiple periodic parts for a fixed wave vector. The wave vector is not directly related to the energy with Bloch waves and there can be multiple Bloch waves corresponding to the same energy. It is possible for eigenstates of the Hamiltonian to have the form of a continuous superposition of periodic functions with different wave vectors.
  • #1
jostpuur
2,116
19
According to the Bloch's theorem, the solutions of SE in a periodic potential may be written as superpositions of Bloch waves. But what kind of superpositions are these? There is the continuous wave vector parameter, over which we can integrate just like in forming free wave packets, but what about the cardinality of solutions for some fixed wave vector. Are the wave equations for fixed wave vector always like this

[tex]
\psi(x) = \sum_j u_j(x)e^{ikx},
[/tex]

where [itex]u_j(x)[/itex] is some sequence (or finite amount) of periodic functions, or could they be like this

[tex]
\psi(x) = \int d\alpha\; u(x,\alpha) e^{ikx}
[/tex]

where we have periodic functions [itex]x\mapsto u(x,\alpha)[/itex] for each [itex]\alpha[/itex], where [itex]\alpha[/itex] is a continuous parameter?

EDIT: Now I see that this is a very strange question, because those superpositions of periodic functions (with same periodicity) are still periodic. I'm not sure what I was thinking... I think I was thinking about how to write superpositions in respect to the wave vector k, but then changed the question while typing this. Can there even be several periodic parts u(x) for some fixed wave vector? Perhaps I should start writing these questions on paper before posting them? :frown:
 
Last edited:
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  • #2
The wave vector k is not directly related to the energy with Bloch waves. How many different Bloch waves

[tex]
\psi_j(x) = u_j(x) e^{ik_j x}
[/tex]

can there be corresponding to the same energy? Could there be eigenstates of the Hamiltonian which have the form

[tex]
\psi(x) = \int d\alpha\; \psi_{\alpha}(x) = \int d\alpha\; u(x,\alpha) e^{ik(\alpha) x}?
[/tex]
 
  • #3


The cardinality of Bloch waves refers to the number of unique solutions that can be formed using the Bloch's theorem. These solutions are superpositions of Bloch waves, which are characterized by a continuous wave vector parameter. This means that for each fixed wave vector, there is an infinite number of possible solutions, each corresponding to a different choice of the continuous parameter.

In the first equation provided, the solutions are written as a sum over a finite or countably infinite number of periodic functions, which are multiplied by the exponential term. This is a valid representation of Bloch waves, as each term in the sum represents a different solution.

In the second equation, the solutions are written as an integral over a continuous parameter, with each term corresponding to a different periodic function. This is also a valid representation, as the integral captures all possible solutions for a fixed wave vector.

It is important to note that in both cases, the solutions are still periodic, as the exponential term ensures that the overall wave function remains periodic. Therefore, there can be multiple periodic parts for a fixed wave vector, but they will always combine to form a periodic solution.

In conclusion, the cardinality of Bloch waves is infinite, as there are an infinite number of unique solutions that can be formed using the Bloch's theorem. The specific form of the superposition may vary, but all solutions will be periodic in nature.
 

1. What is the cardinality of bloch waves?

The cardinality of bloch waves refers to the number of unique states or modes that can exist in a given crystal lattice. It is a measure of the complexity of the wavefunction in a solid and is dependent on factors such as the crystal structure and the number of atoms in the unit cell.

2. How is the cardinality of bloch waves determined?

The cardinality of bloch waves is determined by analyzing the band structure of a crystal, which is a graph representing the allowed energy levels for electrons in the solid. The number of bands in the band structure corresponds to the cardinality of bloch waves, with each band representing a unique state.

3. What is the significance of the cardinality of bloch waves?

The cardinality of bloch waves is important in understanding the electronic properties of crystalline materials. It affects the electrical conductivity, optical properties, and thermal properties of solids, as well as their response to external forces such as magnetic fields.

4. Can the cardinality of bloch waves be changed?

Yes, the cardinality of bloch waves can be altered by changing the crystal structure or the number of atoms in the unit cell. This can be achieved through external forces, such as strain or pressure, or by introducing impurities into the crystal lattice.

5. How does the cardinality of bloch waves relate to the concept of band gaps?

The cardinality of bloch waves is directly related to the presence or absence of a band gap in the band structure of a crystal. A larger cardinality indicates a higher number of allowed energy levels, which can lead to the formation of band gaps in the energy spectrum. The size and location of these band gaps can have significant effects on the properties of the solid.

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