Why Does the Crystal Model Use Squared Combinations for State Count?

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In summary, the conversation discusses an example in a textbook of statistical mechanics regarding an idealized crystal with N lattice points and N interstitial positions. It is mentioned that the energy needed to remove an atom from a lattice site to an interstitial position is represented by E, and the equilibrium number of atoms occupying interstitial sites is represented by n. The conversation then focuses on finding the number of possible configurations given by the combination C_N^n. The example in the textbook provides the number of states as \Omega = (C_N^n)^2 without further explanation, but it is clarified that this is because the atoms must come from somewhere and have left gaps behind them. The total number of ways to choose the atoms from and to is NC_n.
  • #1
KFC
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In textbook of statistical mechanics, there is an example considering an idealization of a crystal which has N lattice points and the same number of interstitial positions (places between the lattice points where atoms can reside). Let E be the energy necessary to remove an atom from a lattice site to an interstitial position and let n be the number of
atoms occupying interstitial sites in equilibrium. Now try to find the number of state

It is quite easy to think about this: choose n atoms from N atoms to fill n interstitial positions, number of possible configuration is given by combination


[tex]C_{N}^n = \frac{N!}{n!(N-n)!}[/tex]

I think the number of state should be

[tex]\Omega = C_{N}^n = \frac{N!}{n!(N-n)!}[/tex]

but the example just put

[tex]\Omega = \left(C_{N}^n\right)^2 = \left(\frac{N!}{n!(N-n)!}\right)^2[/tex]

without saying why. Do you think it is a mistake?
 
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  • #2
KFC said:
… an idealization of a crystal which has N lattice points and the same number of interstitial positions (places between the lattice points where atoms can reside).
Let E be the energy necessary to remove an atom from a lattice site to an interstitial position and let n be the number of
atoms occupying interstitial sites in equilibrium.
Now try to find the number of state

the example just put

[tex]\Omega = \left(C_{N}^n\right)^2 = \left(\frac{N!}{n!(N-n)!}\right)^2[/tex]

without saying why. Do you think it is a mistake?

Hi KFC! :smile:

the atoms have to come from somewhere,

and they've left gaps behind them …

so there are NCn ways of choosing where they're from, and NCn ways of choosing where they're going. :wink:
 
  • #3
tiny-tim said:
Hi KFC! :smile:

the atoms have to come from somewhere,

and they've left gaps behind them …

so there are NCn ways of choosing where they're from, and NCn ways of choosing where they're going. :wink:

Got it. Thanks tiny-tim, you help me a lot.
 

What does "Don't understand state number" mean?

"Don't understand state number" is a phrase commonly used in computer programming when an error occurs in the code related to a state or condition within the program. It means that the program is unable to interpret or process the state or condition specified.

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