What is self and air broadening effects?

In summary, self and air broadening effects, also known as pressure broadening, refer to the broadening of spectral lines in atmospheric modeling due to interactions between air molecules. This effect can change the accuracy of atmospheric modeling and is an important factor to consider when studying emission lines from dense plasmas and thermal radiation interacting with the atmosphere. While there is no exact theory to describe pressure broadening, there are various sources available for further technical information on the topic.
  • #1
nordmoon
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What is self and air broadening effects? I have read that they appear in atmospheric modelling. Is this pressure broadening?
 
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  • #2
nordmoon said:
What is self and air broadening effects? I have read that they appear in atmospheric modelling. Is this pressure broadening?

There is a "broadening" in spectral lines of emission of radiation from a gas. This is quite important for remote sensing by satellites with microwave sounders, and also for modeling how radiation interacts with the atmosphere. It is also relevant to study of emission lines in the spectrum from a dense plasma, such as the atmosphere of a star.

For problems relating to how thermal radiation interacts with an atmosphere, the relevant effect is called "pressure broadening" or "collisional broadening"; the collisions between atoms in a dense gas can alter the energy of radiation emission, which broadens the corresponding spectral line. It's a rather horribly complicated effect to model accurately; in fact I understand there is no exact theory to describe the broadening effects of pressure on spectral lines; although there are adequate heuristic descriptions.

Wikipedia gives a brief summary of the kinds of broadening of spectral lines that can occur; and this may help give pointer to where to find more detail from more technical sources of information. See Spectral line broadening and shift within the wikipedia article on "Spectral Line".

A good discussion is also available in http://www.sundogpublishing.com/AtmosRad/index.html, by Grant W. Petty (Published 2006, Sundog publishing). The link goes to a webpage for the book and you can browse the first edition for free. Pressure broadening and doppler broadening are discussed in chapter 9.

Cheers -- sylas
 
  • #3


Self and air broadening effects refer to the broadening of spectral lines in atmospheric modeling due to interactions between molecules in the air. This is also known as pressure broadening, as it is caused by the pressure of the air molecules on the spectral lines. When molecules collide with each other, they can cause the spectral lines to broaden, making them appear wider and less distinct. This can affect the accuracy of atmospheric modeling, as it can change the intensity and shape of the spectral lines, which are used to measure atmospheric conditions. Pressure broadening is an important factor to consider in atmospheric modeling, as it can impact the accuracy of data and predictions.
 

What is self broadening?

Self broadening is the effect of a molecule's own collisions with other molecules causing a broadening of its spectral lines. This occurs because the collisions disrupt the energy levels of the molecule, leading to a range of possible energy transitions instead of a single, narrow transition.

What is air broadening?

Air broadening is the effect of collisions between a molecule and surrounding air molecules causing a broadening of its spectral lines. This occurs because the collisions disrupt the energy levels of the molecule, leading to a range of possible energy transitions instead of a single, narrow transition. This effect is more pronounced in dense environments, such as the Earth's atmosphere.

What causes self and air broadening effects?

Self and air broadening effects are caused by collisions between molecules. When molecules collide, they can transfer energy to each other, leading to a broadening of the spectral lines. These collisions can also change the rotational and vibrational energy levels of the molecules, resulting in a broadening of the lines.

How do self and air broadening affect spectroscopy?

Self and air broadening can affect spectroscopy by causing the spectral lines of a molecule to broaden and overlap, making it more difficult to accurately measure the energy transitions of the molecule. This can make it challenging to identify the specific molecule present in a sample or to accurately measure its concentration.

Can self and air broadening be controlled or corrected for?

Self and air broadening can be controlled or corrected for by using various techniques such as pressure broadening, where the pressure of the sample is increased to decrease the effects of collisions. Additionally, advanced data analysis techniques can be used to deconvolute the effects of broadening and accurately measure the energy transitions of a molecule.

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