What Are Surface Plasmons and How Do They Relate to Maxwell's Equations?

  • Context: Graduate 
  • Thread starter Thread starter alexyan
  • Start date Start date
  • Tags Tags
    Resonance
Click For Summary

Discussion Overview

The discussion centers around the concept of surface plasmons and their relationship to Maxwell's equations, exploring the nature of plasmonic resonance, its occurrence in different spectra, and the underlying physics involving electrons and electromagnetic waves. The scope includes theoretical explanations, conceptual clarifications, and some references to practical implications.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants describe surface plasmon resonance as a phenomenon occurring at metal/dielectric interfaces, characterized by a sharp dip in reflectivity due to energy coupling into surface plasmon modes.
  • There are mentions of bulk plasmon resonances, although some participants express less familiarity with this type.
  • One participant notes that surface plasmon resonance can occur in the visible spectrum and is sensitive to the refractive index of the dielectric layer, which could be useful for measuring changes in fluids.
  • Another participant questions how surface plasmon resonance can propagate along the interface if energy absorption occurs during resonance, indicating a potential misunderstanding of the propagation mechanism.
  • Some participants assert that surface plasmons are solutions to Maxwell's equations, with one elaborating on the relationship between plasmons and quasiparticles, emphasizing the role of conduction electrons and their interactions with electromagnetic waves.
  • There is a discussion about the quantization of plasma oscillations and how this relates to the description of surface plasmons in the context of quantum mechanics.

Areas of Agreement / Disagreement

Participants express a variety of views on the nature of surface plasmons, their propagation, and their relationship to Maxwell's equations. There is no clear consensus, as some participants challenge or refine earlier claims while others provide differing perspectives on the definitions and implications of plasmons.

Contextual Notes

Some limitations in the discussion include the dependence on specific definitions of plasmons and the unresolved nature of certain mathematical steps related to their description in quantum mechanics versus classical electromagnetism.

alexyan
Messages
16
Reaction score
0
what is "plasmonic resonance"

hi, could somebody who is familiy with "plasmonic resonance" tell me about it?

thank you!
 
Physics news on Phys.org
Sorry. No relation of mine.
 
Surface Plasmon resonances are found on metal/dielectric interfaces.

A surface plasmon resonance manifests itself as a sharp dip in the reflectivity of a metal surface when varying the angle of incidence. This is because the energy of the incident wave, rather than being reflected, is coupled into surface plasmon modes that propagate along the surface of the metal.

There are also bulk plasmon resonances that occur within the volume of the metal itself, although I am not as familiar with this type of resonance.

Claude.
 
Hi Claude;
Does this occur within the visual spectrum? I've noticed that sometimes metal is difficult to look at without getting a headache because I can't seem to focus on it. It would be a lot more dignified if there were a physical cause as opposed to me just being nuts. (I am nuts, of course, but that's totally beside the point right now.)
 
plasmons

Plamons do occur in the visible.

Think of the free electrons in a metal sloshing about like water in a bucket.
If you shine tunable monochromatic light on the metal and scan the wavelength, at certain frequencies(wavelengths) there can be a collective excitation of these free electrons.(absorption). This is what is known as a plasmon resonance.
 
Surface Plasmon Resonance also commonly occurs in the visible. The neat thing about SPR is that the resonance frequency is very sensitive to the refractive index of the dielectric layer on top of the metal layer, making it a very simple way of measuring subtle refractive index changes in fluids for example.

You wouldn't notice this effect though by just looking at metal though since the spectral dip is quite narrow.

Claude.
 
Last edited:
Hi, Claude,
Thank you for your helpful reply. I do not understand how "Surface Plasmon Resonance" still can propagate along the interface. my understanding is when Resonance happens energy will stop transmiiting since plasma absorb and release energy. am I right?
 
alexyan said:
hi, could somebody who is familiy with "plasmonic resonance" tell me about it?

thank you!

you are referring to plasmons , right ?

marlon
 
Surface Plasmons are solutions to Maxwell's equations for metal/dielectric interface. Surface Plasmons also satisfy the wave equation, hence they are also propagating solutions to Maxwell's equations. In addition to this, they are also bound solutions in some cirumstances (much like the fields in an optic fibre for instance).

Surface Plasmons consist of two evanescent fields on either side of the interface. These plasmons propagate along the surface of the metal, however they still undergo absorption, diffraction etc.

Claude.
 
  • #10
Claude Bile said:
Surface Plasmons are solutions to Maxwell's equations for metal/dielectric interface.

I am just wondering about this definition. I just wanted to make a little remark, so i am not saying this definition is wrong or anything.

In college i was introduced to plasmons within the context of many particle-physics. I learned about the use of quasiparticles and it is within this context i encountered plsamons. So basically a bit like the Wikipedia presentation of plasmons.

So plasmons are quasiparticles (ie particles + their interactions = quasiparticles that yield uncoupled differential equations to describe the dynamics). Morespecifically the particles here are (conduction-)electrons and the interaction is between the electrons and some incident EM-wave(photons). If the electric field has a certain frequence the above denoted electrons will jointly move back and forth as a respons to this E-field. In other words these electrons form an oscillation of charge carriers. This oscillaton is quatisized and the resulting "particles" are plasmons (just like the phonons are particles associated with lattice vibration quantization).

Once this is introduced, you get the story of the plasma frequence and the optial properties of metals (ie the screening of the incident -field by the joint motion of the conduction electrons)...


My question is how surface plasmons are solutions of the Maxwell equations ? I mean, what about the electrons being described by the QM ? The way i see it, the EM-part of plasmons only arises in the incident EM-field but in the actual interaction with electrons and after that, the quantization of the resulting plasma-oscillations (the joint oscillatory motion of the electrons as a response to the incident EM-field) which we call plsamons, requires a whole lot more

regards
marlon
 

Similar threads

Replies
4
Views
12K
Replies
1
Views
2K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
1
Views
2K
  • · Replies 2 ·
Replies
2
Views
7K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 5 ·
Replies
5
Views
9K
  • · Replies 2 ·
Replies
2
Views
3K