Activity of daugther isotope in secular equilibrium

In summary, the equation that regulates the number of decays from B, ##N_B##, is given by ${\frac {\mathrm {d} N_{B}}{\mathrm {d} t}}=-\lambda _{B}N_{B}+\lambda _{A}N_{A}$. The concept of activity, which refers to the number of decays per time, is often used to simplify this equation in cases where ##\lambda_A << \lambda_B##. In such cases, the activity of B is approximated as ##\lambda_B N_B##, which is equivalent to the activity of A. This is because the A->B decay is not relevant for the activity of B, but it indirectly
  • #1
crick
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4
Consider chain of two radioactive decays ##A \to B\to C##. The equation that regulates ##N_B## is

$${\frac {\mathrm {d} N_{B}}{\mathrm {d} t}}=-\lambda _{B}N_{B}+\lambda _{A}N_{A}$$

I can't understand why the activity of ##B## is get as ##\lambda_B N_B##, for example at page 20 here http://www.umich.edu/~ners311/CourseLibrary/bookchapter13.pdf. In my view that the activity should be ##-\lambda _{B}N_{B}+\lambda _{A}N_{A}## instead, i.e. ##dN_B/dt## itself.

In particular, in secular equilibrium, ##\lambda_A << \lambda_B## and it is easy to prove that, as ##t\to \infty## $$\lambda_B N_B \to \lambda_A N_A=Activity_A\sim const $$
But, as in the pdf linked, it is usually said that this should also prove that the activity of B becomes equal to the activity of A. I can't understand if in this particular case it is right to say

$$Activtiy_B \sim \lambda _BN_B$$
 
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  • #2
"Activity of B" means how many decays of B are there per time. The A->B decay is irrelevant for that (although it has an indirect effect via refilling the amount of B).
 

1. What is secular equilibrium?

Secular equilibrium is a state in which the rate of production of a radioactive daughter isotope is equal to the rate of its decay, resulting in a constant activity or number of atoms of the daughter isotope over time.

2. How is secular equilibrium achieved?

Secular equilibrium can be achieved when the parent isotope has a much longer half-life than the daughter isotope, allowing it to continuously produce the daughter isotope at a constant rate.

3. What factors can affect secular equilibrium?

The factors that can affect secular equilibrium include changes in temperature, pressure, and chemical environment, as well as the introduction or removal of other isotopes that can compete with the parent isotope for decay pathways.

4. Why is secular equilibrium important in radioisotope dating?

Secular equilibrium is important in radioisotope dating because it ensures that the measured activity of the daughter isotope accurately reflects the age of the sample, as long as the sample has not been disturbed.

5. How can secular equilibrium be used in practical applications?

Secular equilibrium can be used in practical applications such as in nuclear medicine, where the production and decay of daughter isotopes can be used for diagnostic and therapeutic purposes, and in environmental monitoring to track the decay and distribution of radioactive isotopes in the environment.

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