Al has higher 2nd ionisation energy — why?

In summary, the question is asking for an explanation as to why the second ionization energy of Mg is lower than that of Al, even though Mg has more protons in its nucleus. The solution states that this is because the outer electrons for both elements are in the same energy level, and Al has one more electron in this level, making it harder to remove. Additionally, the second electron being removed is not in a different energy level, as the question suggests, but rather in the same level as the first one removed and the second electron of Al.
  • #1
JessicaHelena
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Homework Statement



The question's in the screenshot attached.

Homework Equations

The Attempt at a Solution


I don't know why (B) would be right. I feel like since for Mg's second ionisation energy, it is going from Na to Ne, and Ne is another energy level, Mg's 2nd ionisation energy should be higher than that of Al, but the answer says otherwise. Why? Please help me understand!
 

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  • #2
I don't know what you mean by "it is going from Na to Ne". It's not Na, it's not Ne. It still has the same number of protons in the nucleus, and that makes it still Mg. An unbalanced Mg ion with more protons than electrons.

The explanation is given in the question. The outer electrons for both Mg and Al are in shell #3. Mg has two outer electrons, Al has three. With a second ionization energy in both cases it is level 3 electrons you are removing. Mg has 12 protons in its nucleus and Al has 13, so Al has a stronger force holding the electrons. It takes more energy to peel them away.

JessicaHelena said:
Ne is another energy level,
I sort of get what you're trying to say, but it's not true. The second electron you're removing is not in another level, it's the second electron of level 3. Same level as the first one you removed. And same level as the second electron of Al.
 

1. Why does Al have a higher 2nd ionisation energy compared to other elements?

Aluminum (Al) has a higher 2nd ionisation energy because it has a stable electron configuration with a full outer shell of electrons. This makes it more difficult to remove an electron from Al compared to other elements that have a partially filled outer shell.

2. How does the atomic structure of Al contribute to its higher 2nd ionisation energy?

The atomic structure of Al has 13 protons and 13 electrons. The first ionization energy involves removing an electron from the outermost shell, leaving Al with a stable configuration of 12 electrons. However, the second ionization energy requires removing an electron from the now stable inner shell, which requires more energy.

3. Does the atomic radius of Al affect its 2nd ionisation energy?

Yes, the atomic radius of Al does have an impact on its 2nd ionisation energy. As the atomic radius decreases, the outermost electrons are held more tightly by the nucleus, making it harder to remove an electron and increasing the ionization energy.

4. How does the shielding effect play a role in Al's higher 2nd ionisation energy?

The shielding effect refers to the inner electrons in an atom blocking the attraction between the nucleus and outer electrons. In Al, the 2nd ionization energy involves removing an electron from the stable inner shell, which is more shielded from the nucleus compared to the outer shell. This makes it more difficult to remove an electron and results in a higher 2nd ionization energy.

5. Is the 2nd ionisation energy of Al always higher than the 1st ionisation energy?

Yes, the 2nd ionisation energy of Al is always higher than the 1st ionisation energy. This is because the first ionization energy involves removing an electron from the outermost shell, which is less stable compared to the inner shell. The second ionization energy involves removing an electron from the now stable inner shell, requiring more energy.

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