Average Speed for Maxwell's Distribution of Molecular Speed

In summary, the Maxwell-Boltzmann equation can be used to find the average velocity of molecules by taking the sum of all speeds and dividing by the number of molecules. To solve for the integral in the equation, integration by parts is used, with the first equality being the result of the integration. The process of integration by parts is demonstrated with the example of u = x^2 and dv = x e^{-x^2}dx.
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RaulTheUCSCSlug
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Using the Maxwell-Boltzmann equation above, there is an example in my book (Giancoli 4th edition p. 481) where they use this to find the average velocity. I understand that it would just be the sum of all the speeds of the molecules divided by the number of molecules. But then I'm having trouble on how they did the integration by parts? Could someone walk me through the process?

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Let [itex]a=\frac{m}{2kT}[/itex]
[itex]\int_0^{\infty}v^3e^{-av^2}dv=\frac{1}{a}\int_0^{\infty}ve^{-av^2}dv=\frac{1}{2a^2}=\frac{2k^2T^2}{m^2}[/itex]

The first equality is integration by parts.
 
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  • #3
Do you know how to do integration by parts? [itex] \int u dv = uv - \int v du[/itex] . Try [itex]u = x^2; dv = x e^{-x^2}dx [/itex]
 

1. What is the definition of average speed for Maxwell's distribution of molecular speed?

The average speed for Maxwell's distribution of molecular speed is the average velocity of a group of molecules at a given temperature. It is calculated by finding the sum of the individual molecular speeds and dividing it by the total number of molecules.

2. How is average speed related to temperature in Maxwell's distribution?

In Maxwell's distribution, as temperature increases, the average speed of the molecules also increases. This is because an increase in temperature causes the molecules to have more kinetic energy, leading to faster movement and higher average speed.

3. Can the average speed for Maxwell's distribution of molecular speed be greater than the speed of light?

No, the average speed for Maxwell's distribution of molecular speed cannot be greater than the speed of light. According to the theory of relativity, the speed of light is the maximum speed that any object can attain.

4. How does the mass of molecules affect the average speed in Maxwell's distribution?

The mass of molecules does not directly affect the average speed in Maxwell's distribution. However, lighter molecules tend to have higher average speeds compared to heavier molecules at the same temperature due to their lower inertia.

5. Why is Maxwell's distribution of molecular speed important in chemistry and physics?

Maxwell's distribution of molecular speed is important in chemistry and physics because it helps in understanding the behavior of gases and the relationship between temperature and molecular motion. It also provides a basis for the kinetic theory of gases and explains various phenomena, such as diffusion and effusion.

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